Organic electroluminescence device and electronic apparatus provided with the same

ABSTRACT

An organic electroluminescence device inducting a cathode, an anode, and an emitting layer disposed between the cathode and the anode, wherein the emitting layer includes a compound represented by the following formula (1) and one or more compounds selected from the group consisting of compounds represented by each of formulas (11), (21), (31), (41), (51), (61), (71) and (81). In the formula (1), at least one of R 1  to R 8  is a deuterium atom,

TECHNICAL FIELD

The invention relates to an organic electroluminescence device and an electronic apparatus provided with the organic electroluminescence device.

BACKGROUND ART

When a voltage is applied to an organic electroluminescence device (hereinafter may be referred to as an organic EL device), holes are injected to an emitting layer from an anode and electrons are injected to an emitting layer from a cathode. In the emitting layer, injected holes and electrons are re-combined and excitons are formed.

Although materials for an organic EL device are being improved gradually to increase the performances of the organic EL device (for example, Patent Documents 1 to 6), high performances are further offered. In particular, improvement in lifetime of an organic EL device is an important task relating to a lifetime of commercial products provided with the organic EL device, and thus a material enabling to realize a long-lifetime organic EL device is required.

RELATED ART DOCUMENTS Patent Documents

-   Patent Document 1: WO2017/188111 -   Patent Document 2: Publication of US Patent Application No.     2017/324045 -   Patent Document 3: WO2010/099534 -   Patent Document 4: WO2010/135395 -   Patent Document 5: WO2010/071362 -   Patent Document 6: WO2018/066830

SUMMARY OF THE INVENTION

An object of the invention is to provide an organic EL device having a long lifetime, and to provide an electronic apparatus provided with the organic EL device.

As a result of extensive studies, the inventors have found that an organic EL device having a long lifetime can be obtained by using compounds having a specific structure in an emitting layer of the organic EL device in combination, and they have achieved the invention.

According to the invention, the following organic EL device and electric apparatus can be provided.

1. An organic electroluminescence device comprising:

a cathode,

an anode, and

an emitting layer disposed between the cathode and the anode, wherein

the emitting layer comprises a compound represented by the following formula (1) and one or more compounds selected from the group consisting of compounds represented by each of formulas (11), (21), (31), (41), (51), (61), (71) and (81):

wherein in the formula (1),

R₁ to R₈ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted a unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

when two or more of R₉₀₁ to R₉₀₇ exist, two or more of R₉₀₁ to R₉₀₇ may be the same with or different from each other;

at least one of R₁ to R₈ is a deuterium atom;

two or more adjacent groups of R₁ to R₄ and two or more adjacent groups of R₅ to R₈ do not form a ring;

L₁ and L₂ are independently

a single bond, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms;

Ar is

a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

one of R₁₁ to R₁₈ is a single bond bonding to L₂;

R₁₁ to R₁₈ which are not single bonds bonding to L₂ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in R₁ to R₈; and

two or more adjacent groups of R₁₁ to R₁₈ do not form a ring;

wherein, in the formula (11),

one or more pairs of two or more adjacent groups of R₁₀₁ to R₁₁₀ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

at least one of R₁₀₁ to R₁₁₀ is a monovalent group represented by the formula (12);

R₁₀₁ to R₁₁₀ that do not form the substituted or unsubstituted, saturated or unsaturated ring and that are not a monovalent group represented by the following formula (12) are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (12), Ar₁₀₁ and Ar₁₀₂ are independently

a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

L₁₀₁ to L₁₀₃ are independently

a single bonded, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms;

wherein, in the formula (21),

Zs are independently CR_(a) or N;

A1 ring and A2 ring are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

when a plurality of R_(a)s exist, one or more pairs of two or more adjacent groups of R_(a) are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

when a plurality of R_(b)s exist, one or more pairs of two or more adjacent groups of R_(b) are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

when a plurality of R_(c)s exist, one or more pairs of two or more adjacent groups of R_(c) are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

n21 and n22 are independently an integer of 0 to 4;

R_(a) to R_(c) that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (31),

one or more pairs of two or more adjacent groups of R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted saturated or unsaturated ring;

R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently a hydrogen atom,

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₃₂₁ and R₃₂₂ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (41),

a ring, b ring and c ring are independently

a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

R₄₀₁ and R₄₀₂ are independently bonded to the a ring, the b ring or the c ring to form a substituted or unsubstituted heterocyclic ring or do not form a substituted or unsubstituted heterocyclic ring;

R₄₀₁ and R₄₀₂ that do not form the substituted or unsubstituted heterocyclic ring are independently

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

wherein, in the formula (51),

r ring is a ring represented by the formula (52) or formula (53) which is fused to an adjacent ring at an arbitrary position;

q ring and s ring are independently a ring represented by the formula (54) which is fused to an adjacent ring at an arbitrary position;

p ring and t ring are independently a ring represented by the formula (55) or the formula (56) which is fused to an adjacent ring at an arbitrary position;

when a plurality of R₅₀₁s exist, adjacent R₅₀₁s are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

X₅₀₁ is an oxygen atom, a sulfur atom, or NR₅₀₂;

R₅₀₁ and R₅₀₂ that do not form the substituted or unsubstituted saturated or unsaturated ring are

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

Ar₅₀₁ and Ar₅₀₂ are independently

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

L₅₀₁ is

a substituted or unsubstituted alkylene group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenylene group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynylene group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkylene group having 3 to 50 ring carbon atoms, a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 50 ring atoms;

m1 is an integer of 0 to 2, m2 is an integer of 0 to 4, m3s are independently an integer of 0 to 3, and m4s are independently an integer of 0 to 5; when a plurality of R₅₀₁s exist the R₅₀₁s may be the same or different;

wherein, in the formula (61),

at least one pair of R₆₀₁ and R₆₀₂, R₆₀₂ and R₆₀₃, and R₆₀₃ and R₆₀₄ are bonded with each other to form a divalent group represented by the formula (62);

at least one pair of R₆₀₅ and R₆₀₆, R₆₀₅ and R₆₀₇, and R₆₀₇ and R₆₀₈ are bonded with each other to form a divalent group represented by formula (63);

at least one of R₆₀₁ to R₆₀₄ that does not form the divalent group represented by the formula (62), and R₆₁₁ to R₆₁₄ is a monovalent group represented by the following formula (64);

at least one of R₆₀₅ to R₆₀₆ that do not form the divalent group represented by the formula (63), and R₆₂₁ to R₆₂₄ is a monovalent group represented by the following formula (64);

X₆₀₁ is an oxygen atom, a sulfur atom, or NR₆₀₉;

R₆₀₁ to R₆₀₆ that do not form the divalent group represented by the formulas (62) and (63) and that is not the monovalent group represented by the formula (64), R₆₁₁ to R₆₁₄ and R₆₁₄ to R₆₂₄ that are not the monovalent group represented by the formula (64), and R₆₀₉ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (64), Ar₆₀₁ and Ar₆₀₂ are independently

a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

L₆₀₁ to L₆₀₃ are independently

a single bonded, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms, or a divalent linking group formed by bonding 2 to 4 above mentioned groups;

wherein, in the formula (71),

A₇₀₁ ring and A₇₀₂ ring are independently

a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

One or more rings selected from the group consisting of A₇₀₁ ring and A₇₀₂ ring are bonded to the bond * of the structure represented by the following formula (72);

wherein, in the formula (72),

A₇₀₃ rings are independently

a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

X₇₀₁ is NR₇₀₃, C(R₇₀₄)(R₇₀₅), Si(R₇₀₆) (R₇₀₇), Ge(R₇₀₈) (R₇₀₉), O, S or Se;

R₇₀₁ and R₇₀₂ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring or do not form a substituted or unsubstituted saturated or unsaturated ring;

R₇₀₁ and R₇₀₂ that do not form the substituted or unsubstituted, saturated or unsaturated ring, and

R₇₀₃ to R₇₀₉ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (81),

A₈₀₁ ring is a ring represented by the formula (82) which is fused to an adjacent ring at an arbitrary position;

A₈₀₂ ring is a ring represented by the formula (83) which is fused to an adjacent ring at an arbitrary position;

two bonds * bond to A₈₀₃ ring at an arbitrary position;

X₈₀₁ and X₈₀₂ are independently C(R₈₀₃)(R₈₀₄), Si(R₈₀₅)(R₈₀₆), an oxygen atom, or a sulfur atom;

A₈₀₃ ring is a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

Ar₈₀₁ is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₈₀₁ to R₈₀₆ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

m801 and m802 are independently an integer of 0 to 2; when these are 2, a plurality of R₈₀₁s or R₈₀₂s may be the same or different;

a801 is an integer of 0 to 2; when a801 is 0 or 1, the structure in the parentheses indicated by “3-a801” may be the same as or different from each other, when a801 is 2, Ar₈₀₁s may be the same or different from each other.

2. An electronic apparatus provided with the organic electroluminescence device according to the above 1.

According to the invention, an organic EL device having a long lifetime, and an electronic apparatus provided with the organic EL device can be provided.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a view showing a schematic configuration of one embodiment of the organic EL device of the invention.

MODE FOR CARRYING OUT THE INVENTION Definition

In the present specification, a hydrogen atom means an atom including isotopes different in the number of neutrons, namely, a protium, a deuterium and a tritium.

In the present specification, to a bondable position in which a symbol such as “R”, or “D” representing a deuterium atom is not specified in a chemical formula, a hydrogen atom, that is, a light hydrogen atom, a deuterium atom, or a tritium atom is bonded thereto.

In the present specification, a term “ring carbon atoms” represents the number of carbon atoms among atoms forming a subject ring itself of a compound having a structure in which atoms are bonded in a ring form (for example, a monocyclic compound, a fused ring compound, a cross-linked compound, a carbocyclic compound or a heterocyclic compound). When the subject ring is substituted by a substituent, the carbon contained in the substituent is not included in the number of ring carbon atoms. The same shall apply to the “ring carbon atoms” described below, unless otherwise noted. For example, a benzene ring has 6 ring carbon atoms, a naphthalene ring has 10 ring carbon atoms, a pyridine ring has 5 ring carbon atoms, and a furan ring has 4 ring carbon atoms. Further, for example, a 9,9-diphenylfluorenyl group has 13 ring carbon atoms, and a 9,9′-spirobifluorenyl group has 25 ring carbon atoms.

Further, when the benzene ring or the naphthalene ring is substituted by an alkyl group as a substituent, for example, the number of carbon atoms of the alkyl group is not included in the ring carbon atoms.

In the present specification, a term “ring atoms” represents the number of atoms forming a subject ring itself of a compound having a structure in which atoms are bonded in a ring form (for example, a monocycle, a fused ring and a ring assembly) (for example, a monocyclic compound, a fused ring compound, a cross-linked compound, a carbocyclic compound or a heterocyclic compound). The term “ring atoms” does not include atoms which do not form the ring (for example, a hydrogen atom which terminates a bond of the atoms forming the ring) or atoms contained in a substituent when the ring is substituted by the substituent. The same shall apply to the “ring atoms” described below, unless otherwise noted. For example, a pyridine ring has 6 ring atoms, a quinazoline ring has 10 ring atoms, and a furan ring has 5 ring atoms. A hydrogen atom bonded with a carbon atom of the pyridine ring or the quinazoline ring or an atom forming the substituent is not included in the number of the ring atoms.

In the present specification, a term “XX to YY carbon atoms” in an expression of “substituted or unsubstituted ZZ group having XX to YY carbon atoms” represents the number of carbon atoms when the ZZ group is unsubstituted. The number of carbon atoms of a substituent when the ZZ group is substituted is not included. Here, “YY” is larger than “XX”, and “XX” and “YY” each mean an integer of 1 or more.

In the present specification, a term “XX to YY atoms” in an expression of “substituted or unsubstituted ZZ group having XX to YY atoms” represents the number of atoms when the ZZ group is unsubstituted. The number of atoms of a substituent when the group is substituted is not included. Here, “YY” is larger than “XX”, and “XX” and “YY” each mean an integer of 1 or more.

A term “unsubstituted” in the case of “substituted or unsubstituted ZZ group” means that the ZZ group is not substituted by a substituent, and a hydrogen atom is bonded therewith. Alternatively, a term “substituted” in the case of “substituted or unsubstituted ZZ group” means that one or more hydrogen atoms in the ZZ group are substituted by a substituent. Similarly, a term “substituted” in the case of “BB group substituted by an AA group” means that one or more hydrogen atoms in the BB group are substituted by the AA group.

Hereinafter, the substituent described herein will be described.

The number of the ring carbon atoms of the “unsubstituted aryl group” described herein is 6 to 50, preferably 6 to 30, and more preferably 6 to 18, unless otherwise specified.

The number of the ring carbon atoms of the “unsubstituted heterocyclic group” described herein is 5 to 50, preferably 5 to 30, and more preferably 5 to 18, unless otherwise specified.

The number of the carbon atoms of the “unsubstituted alkyl group” described herein is 1 to 50, preferably 1 to 20, and more preferably 1 to 6, unless otherwise specified.

The number of the carbon atoms of the “unsubstituted alkenyl group” described herein is 2 to 50, preferably 2 to 20, and more preferably 2 to 6, unless otherwise specified.

The number of the carbon atoms of the “unsubstituted alkynyl group” described herein is 2 to 50, preferably 2 to 20, and more preferably 2 to 6, unless otherwise specified.

The number of the ring carbon atoms of the “unsubstituted cycloalkyl group” described herein is 3 to 50, preferably 3 to 20, and more preferably 3 to 6, unless otherwise specified.

The number of the ring carbon atoms of the “unsubstituted arylene group” described herein is 6 to 50, preferably 6 to 30, and more preferably 6 to 18, unless otherwise specified.

The number of the ring atoms of the “unsubstituted divalent heterocyclic group” described herein is 5 to 50, preferably 5 to 30, and more preferably 5 to 18, unless otherwise specified.

The number of the carbon atoms of the “unsubstituted alkylene group” described herein is 1 to 50, preferably 1 to 20, and more preferably 1 to 6, unless otherwise specified.

Specific examples (specific example group G1) of the “substituted or unsubstituted aryl group” described herein include an unsubstituted aryl group and a substituted aryl group described below. (Here, a term “unsubstituted aryl group” refers to a case where the “substituted or unsubstituted aryl group” is the “unsubstituted aryl group,” and a term “substituted aryl group” refers to a case where the “substituted or unsubstituted aryl group” is the “substituted aryl group”. Hereinafter, a case of merely “aryl group” includes both the “unsubstituted aryl group” and the “substituted aryl group”.

The “substituted aryl group” refers to a case where the “unsubstituted aryl group” has a substituent, and specific examples thereof include a group in which the “unsubstituted aryl group” has the substituent, and a substituted aryl group described below. It should be noted that examples of the “unsubstituted aryl group” and examples of the “substituted aryl group” listed herein are only one example, and the “substituted aryl group” described herein also includes a group in which a group in which “unsubstituted aryl group” has a substituent further has a substituent, and a group in which “substituted aryl group” further has a substituent, and the like.

An unsubstituted aryl group:

a phenyl group, a p-biphenyl group, a m-biphenyl group, an o-biphenyl group, a p-terphenyl-4-yl group, a p-terphenyl-3-yl group, a p-terphenyl-2-yl group, a m-terphenyl-4-yl group, a m-terphenyl-3-yl group, a m-terphenyl-2-yl group, an o-terphenyl-4-yl group, an o-terphenyl-3-yl group, an o-terphenyl-2-yl group, a 1-naphthyl group, a 2-naphthyl group, an anthryl group, a benzanthryl group, a phenanthryl group, a benzophenanthryl group, a phenalenyl group, a pyrenyl group, a chrysenyl group, a benzochrysenyl group, a triphenylenyl group, a benzotriphenylenyl group, a tetracenyl group, a pentacenyl group, a fluorenyl group, a 9,9′-spirobifluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a fluoranethenyl group, a benzofluoranethenyl group, and a perylenyl group.

A substituted aryl group:

an o-tolyl group, a m-tolyl group, a p-tolyl group, a p-xylyl group, a m-xylyl group, an o-xylyl group, a p-isopropyl phenyl group, a m-isopropyl phenyl group, an o-isopropyl phenyl group, a p-t-butylphenyl group, a m-t-butylphenyl group, an o-t-butylphenyl group, a 3,4,5-trimethylphenyl group, a 9,9-dimethylfluorenyl group, a 9,9-diphenylfluorenyl group a 9,9-di(4-methylphenyl)fluorenyl group, a 9,9-di(4-isopropylphenyl)fluorenyl group, a 9,9-di(4-t-butylphenyl)fluorenyl group, a cyanophenyl group, a triphenylsilylphenyl group, a trimethylsilylphenyl group, a phenylnaphthyl group, and a naphthylphenyl group.

The “heterocyclic group” described herein is a ring group having at least one hetero atom in the ring atom. Specific examples of the hetero atom include a nitrogen atom, an oxygen atom, a sulfur atom, a silicon atom, a phosphorus atom and a boron atom.

The “heterocyclic group” described herein may be a monocyclic group, or a fused ring group.

The “heterocyclic group” described herein may be an aromatic heterocyclic group, or an aliphatic heterocyclic group.

Specific examples (specific example group G2) of the “substituted or unsubstituted heterocyclic group” include an unsubstituted heterocyclic group and a substituted heterocyclic group described below. (Here, the unsubstituted heterocyclic group refers to a case where the “substituted or unsubstituted heterocyclic group” is the “unsubstituted heterocyclic group,” and the substituted heterocyclic group refers to a case where the “substituted or unsubstituted heterocyclic group” is the “substituted heterocyclic group”. Hereinafter, the case of merely “heterocyclic group” includes both the “unsubstituted heterocyclic group” and the “substituted heterocyclic group”.

The “substituted heterocyclic group” refers to a case where the “unsubstituted heterocyclic group” has a substituent, and specific examples thereof include a group in which the “unsubstituted heterocyclic group” has a substituent, and a substituted heterocyclic group described below. It should be noted that examples of the “unsubstituted heterocyclic group” and examples of the “substituted heterocyclic group” listed herein are merely one example, and the “substituted heterocyclic group” described herein also includes a group in which “unsubstituted heterocyclic group” which has a substituent further has a substituent, and a group in which “substituted heterocyclic group” further has a substituent, and the like.

An unsubstituted heterocyclic group having a nitrogen atom:

a pyrrolyl group, an imidazolyl group, a pyrazolyl group, a triazolyl group, a tetrazolyl group, an oxazolyl group, an isoxazolyl group, an oxadiazolyl group, a thiazolyl group, an isothiazolyl group, a thiadiazolyl group, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, an indolyl group, an isoindolyl group, an indolizinyl group, a quinolizinyl group, a quinolyl group, an isoquinolyl group, a cinnolyl group, a phthalazinyl group, a quinazolinyl group, a quinoxalinyl group, a benzimidazolyl group, an indazolyl group, a phenanthrolinyl group, a phenanthridinyl group an acridinyl group, a phenazinyl group, a carbazolyl group, a benzocarbazolyl group, a morpholino group, a phenoxazinyl group, a phenothiazinyl group, an azacarbazolyl group, and a diazacarbazolyl group.

An unsubstituted heterocyclic group having an oxygen atom:

a furyl group, an oxazolyl group, an isoxazolyl group, an oxadiazolyl group, a xanthenyl group, a benzofuranyl group, an isobenzofuranyl group, a dibenzofuranyl group, a naphthobenzofuranyl group, a benzooxazolyl group, a benzisoxazolyl group, a phenoxazinyl group, a morpholino group, a dinaphthofuranyl group, an azadibenzofuranyl group, a diazadibenzofuranyl group, an azanaphthobenzofuranyl group, and a diazanaphthobenzofuranyl group.

An unsubstituted heterocyclic group having a sulfur atom:

a thienyl group, a thiazolyl group, an isothiazolyl group, a thiadiazolyl group, a benzothiophenyl group, an isobenzothiophenyl group, a dibenzothiophenyl group, a naphthobenzothiophenyl group, a benzothiazolyl group, a benzisothiazolyl group, a phenothiazinyl group, a dinaphthothiophenyl group, an azadibenzothiophenyl group, a diazadibenzothiophenyl group, an azanaphthobenzothiophenyl group, and a diazanaphthobenzothiophenyl group.

A substituted heterocyclic group having a nitrogen atom:

a (9-phenyl)carbazolyl group, a (9-biphenylyl)carbazolyl group, a (9-phenyl)phenylcarbazolyl group, a (9-naphthyl)carbazolyl group, a diphenylcarbazol-9-yl group, a phenylcarbazol-9-yl group, a methylbenzimidazolyl group, an ethylbenzimidazolyl group, a phenyltriazinyl group, a biphenylyltriazinyl group, a diphenyltriazinyl group, a phenylquinazolinyl group, and a biphenylylquinazolinyl group.

A substituted heterocyclic group having an oxygen atom:

a phenyldibenzofuranyl group, a methyldibenzofuranyl group, a t-butyidibenzofuranyl group, and a monovalent residue of spiro[9H-xanthene-9,9′-[9H]fluorene].

A substituted heterocyclic group having a sulfur atom:

a phenyldibenzothiophenyl group, a methyldibenzothiophenyl group, a t-butyldibenzothiophenyl group, and a monovalent residue of spiro[9H-thiaxantene-9,9′-[9H]fluorene].

A monovalent group derived from the following unsubstituted heterocyclic ring containing at least one of a nitrogen atom, an oxygen atom and a sulfur atom by removal of one hydrogen atom bonded to the ring atoms thereof, and a monovalent group in which a monovalent group derived from the following unsubstituted heterocyclic ring has a substituent by removal of one hydrogen atom bonded to the ring atoms thereof:

In the formulas (XY-1) to (XY-18), X_(A) and Y_(A) are independently an oxygen atom, a sulfur atom, NH or CH₂. However, at least one of X_(A) and Y_(A) is aη oxygen atom, a sulfur atom or NH.

The heterocyclic ring represented by the formulas (XY-1) to (XY-18) becomes a monovalent heterocyclic group having a bond at an arbitrary position.

An expression “the monovalent group derived from the unsubstituted heterocyclic ring represented by the formulas (XY-1) to (XY-18) has a substituent” refers to a case where the hydrogen atom bonded with the carbon atom which constitutes a skeleton of the formulas is substituted by a substituent, or a state in which X_(A) or Y_(A) is NH or CH₂, and the hydrogen atom in the NH or CH₂ is replaced with a substituent

Specific examples (specific example group G3) of the “substituted or unsubstituted alkyl group” include an unsubstituted alkyl group and a substituted alkyl group described below. (Here, the unsubstituted alkyl group refers to a case where the “substituted or unsubstituted alkyl group” is the “unsubstituted alkyl group,” and the substituted alkyl group refers to a case where the “substituted or unsubstituted alkyl group” is the “substituted alkyl group”) Hereinafter, the case of merely “alkyl group” includes both the “unsubstituted alkyl group” and the “substituted alkyl group”.

The “substituted alkyl group” refers to a case where the “unsubstituted alkyl group” has a substituent, and specific examples thereof include a group in which the “unsubstituted alkyl group” has a substituent, and a substituted alkyl group described below. It should be noted that examples of the “unsubstituted alkyl group” and examples of the “substituted alkyl group” listed herein are merely one example, and the “substituted alkyl group” described herein also includes a group in which “unsubstituted alkyl group” has a substituent further has a substituent, a group in which “substituted alkyl group” further has a substituent, and the like.

An unsubstituted alkyl group:

a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group, an isobutyl group, a s-butyl group, and a t-butyl group.

A substituted alkyl group:

a heptafluoropropyl group (including an isomer), a pentafluoroethyl group, a 2,2,2-trifluoroethyl group, and a trifluoromethyl group.

Specific examples (specific example group G4) of the “substituted or unsubstituted alkenyl group” include an unsubstituted alkenyl group and a substituted alkenyl group described below. (Here, the unsubstituted alkenyl group refers to a case where the “substituted or unsubstituted alkenyl group” is the “unsubstituted alkenyl group,” and the substituted alkenyl group refers to a case where the “substituted or unsubstituted alkenyl group” is the “substituted alkenyl group”). Hereinafter, the case of merely “alkenyl group” includes both the “unsubstituted alkenyl group” and the “substituted alkenyl group”.

The “substituted alkenyl group” refers to a case where the “unsubstituted alkenyl group” has a substituent, and specific examples thereof include a group in which the “unsubstituted alkenyl group” has a substituent, and a substituted alkenyl group described below. It should be noted that examples of the “unsubstituted alkenyl group” and examples of the “substituted alkenyl group” listed herein are merely one example, and the “substituted alkenyl group” described herein also includes a group in which “unsubstituted alkenyl group” has a substituent further has a substituent, a group in which “substituted alkenyl group” further has a substituent, and the like.

An unsubstituted alkenyl group and a substituted alkenyl group:

a vinyl group, an allyl group, a 1-butenyl group, a 2-butenyl group, a 3-butenyl group, a 1,3-butanedienyl group, a 1-methylvinyl group, a 1-methylallyl group, a 1,1-dimethylallyl group, a 2-methylallyl group, and a 1,2-dimethylallyl group.

Specific examples (specific example group G5) of the “substituted or unsubstituted alkynyl group” include an unsubstituted alkynyl group described below. (Here, the unsubstituted alkynyl group refers to a case where the “substituted or unsubstituted alkynyl group” is the “unsubstituted alkynyl group”). Hereinafter, a case of merely “alkynyl group” includes both the “unsubstituted alkynyl group” and the “substituted alkynyl group”.

The “substituted alkynyl group” refers to a case where the “unsubstituted alkynyl group” has a substituent, and specific examples thereof include a group in which the “unsubstituted alkynyl group” described below has a substituent.

An unsubstituted alkynyl group:

an ethynyl group.

Specific examples (specific example group G6) of the “substituted or unsubstituted cycloalkyl group” described herein include an unsubstituted cycloalkyl group and a substituted cycloalkyl group described below. (Here, the unsubstituted cycloalkyl group refers to a case where the “substituted or unsubstituted cycloalkyl group” is the “unsubstituted cycloalkyl group,” and the substituted cycloalkyl group refers to a case where the “substituted or unsubstituted cycloalkyl group” is the “substituted cycloalkyl group”). Hereinafter, a case of merely “cycloalkyl group” includes both the “unsubstituted cycloalkyl group” and the “substituted cycloalkyl group”.

The “substituted cycloalkyl group” refers to a case where the “unsubstituted cycloalkyl group” a the substituent, and specific examples thereof include a group in which the “unsubstituted cycloalkyl group” has a substituent, and a substituted cycloalkyl group described below. It should be noted that examples of the “unsubstituted cycloalkyl group” and examples of the “substituted cycloalkyl group” listed herein are merely one example, and the “substituted cycloalkyl group” described herein also includes a group in which “unsubstituted cycloalkyl group” has a substituent further has a substituent, a group in which “substituted cycloalkyl group” further has a substituent, and the like.

An unsubstituted aliphatic ring group:

a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, a 1-adamantyl group, a 2-adamantyl group, a 1-norbornyl group, and a 2-norbornyl group.

A substituted cycloalkyl group:

a 4-methylcyclohexyl group.

Specific examples (specific example group G7) of the group represented by —Si(R₉₀₁)(R₉₀₂)(R₉₀₃) described herein include

—Si(G1)(G1)(G1), —Si(G1)(G2)(G2), —Si(G1)(G1)(G2), —Si(G2)(G2)(G2), —Si(G3)(G3)(G3), —Si(G5)(G5)(G5) and —Si(G6)(G6)(G6).

In which,

G1 is the “aryl group” described in the specific example group G1.

G2 is the “heterocyclic group” described in the specific example group G2.

G3 is the “alkyl group” described in the specific example group G3.

G5 is the “alkynyl group” described in the specific example group G5.

G6 is the “cycloalkyl group” described in the specific example group G6.

Specific examples (specific example group G8) of the group represented by —O—(R₉₀₄) described herein include

—O(G1), —O(G2), —O(G3) and —O(G6).

In which,

G1 is the “aryl group” described in the specific example group G1.

G2 is the “heterocyclic group” described in the specific example group G2.

G3 is the “alkyl group” described in the specific example group G3.

G6 is the “cycloalkyl group” described in the specific example group G6.

Specific examples (specific example group G9) of the group represented by —S—(R₉₀₅) described herein include

—S(G1), —S(G2), —S(G3) and —S(G6).

In which,

G1 is the “aryl group” described in the specific example group G1.

G2 is the “heterocycle group” described in the specific example group G2.

G3 is the “alkyl group” described in the specific example group G3.

G6 is the “cycloalkyl group” described in the specific example group G6.

Specific examples (specific example group G10) of the group represented by —N(R₉₀₆)(R₉₀₇) described herein include

—N(G1)(G1), —N(G2)(G2), —N(G1)(G2), —N(G3)(G3) and —N(G6) (G6).

In which,

G1 is the “aryl group” described in the specific example group G1.

G2 is the “heterocycle group” described in the specific example group G2.

G3 is the “alkyl group” described in the specific example group G3.

G6 is the “cycloalkyl group” described in the specific example group G6.

Specific examples (specific example group G11) of the “halogen atom” described herein include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom.

Specific examples of the “alkoxy group” described herein include a group represented by —O(G3), where G3 is the “alkyl group” described in the specific example group G3. The number of carbon atoms of the “unsubstituted alkoxy group” are 1 to 50, preferably 1 to 30, and more preferably 1 to 18, unless otherwise specified.

Specific examples of the “alkylthio group” described herein include a group represented by —S(G3), where G3 is the “alkyl group” described in the specific example group G3. The number of carbon atoms of the “unsubstituted alkylthio group” are 1 to 50, preferably 1 to 30, and more preferably 1 to 18, unless otherwise specified.

Specific examples of the “aryloxy group” described herein include a group represented by —O(G1), where G1 is the “aryl group” described in the specific example group G1. The number of ring carbon atoms of the “unsubstituted aryloxy group” are 6 to 50, preferably 6 to 30, and more preferably 6 to 18, unless otherwise specified.

Specific examples of the “arylthio group” described herein include a group represented by —S(G1), where G1 is the “aryl group” described in the specific example group G1. The number of ring carbon atoms of the “unsubstituted arylthio group” are 6 to 50, preferably 6 to 30, and more preferably 6 to 18, unless otherwise specified.

Specific examples of the “aralkyl group” described herein include a group represented by -(G3)-(G1), where G3 is the “alkyl group” described in the specific example group G3, and G1 is the “aryl group” described in the specific example group G1. Accordingly, the “aralkyl group” is one embodiment of the “substituted alkyl group” substituted by the “aryl group”. The number of carbon atoms of the “unsubstituted aralkyl group,” which is the “unsubstituted alkyl group” substituted by the “unsubstituted aryl group,” are 7 to 50, preferably 7 to 30, and more preferably 7 to 18, unless otherwise specified.

Specific example of the “aralkyl group” include a benzyl group, a 1-phenylethyl group, a 2-phenylethyl group, a 1-phenylisopropyl group, a 2-phenylisopropyl group, a phenyl-t-butyl group, an a-naphthylmethyl group, a 1-α-naphthylethyl group, a 2-α-naphthylethyl group, a 1-a-naphthylisopropyl group, a 2-a-naphthylisopropyl group, a 3-naphthylmethyl group, a 1-β-naphthylethyl group, a 2-β-naphthylethyl group, a 1-β-naphthylisopropyl group, and a 2-β-naphthylisopropyl group.

The substituted or unsubstituted aryl group described herein is, unless otherwise specified, preferably a phenyl group, a p-biphenyl group, a m-biphenyl group, an o-biphenyl group, a p-terphenyl-4-yl group, a p-terphenyl-3-yl group, a p-terphenyl-2-yl group, a m-terphenyl-4-yl group, a m-terphenyl-3-yl group, a m-terphenyl-2-yl group, an o-terphenyl-4-yl group, an o-terphenyl-3-yl group, an o-terphenyl-2-yl group, a 1-naphthyl group, a 2-naphthyl group, an anthryl group, a phenanthryl group, a pyrenyl group, a chrysenyl group, a triphenylenyl group, a fluorenyl group, a 9,9′-spirobifluorenyl group, a 9,9-diphenylfluorenyl group, ex the like.

The substituted or unsubstituted heterocyclic group described herein is, unless otherwise specified, preferably a pyridyl group, a pyrimidinyl group, a triazinyl group, a quinolyl group, an isoquinolyl group, a quinazolinyl group, a benzimidazolyl group, a phenanthrolinyl group, a carbazolyl group (a 1-carbazolyl group, a 2-carbazolyl group, a 3-carbazolyl group, a 4-carbazolyl group, or a 9-carbazolyl group), a benzocarbazolyl group, an azacarbazolyl group, a diazacarbazolyl group, a dibenzofuranyl group, a naphthobenzofuranyl group, an azadibenzofuranyl group, a diazadibenzofuranyl group, a dibenzothiophenyl group, a naphthobenzothiophenyl group, an azadibenzothiophenyl group, a diazadibenzothiophenyl group, a (9-phenyl)carbazolyl group (a (9-phenyl)carbazol-1-yl group, a (9-phenyl)carbazol-2-yl group, a (9-phenyl)carbazol-3-yl group, or a (9-phenyl)carbazol-4-yl group), a (9-biphenylyl)carbazolyl group, a (9-phenyl)phenylcarbazolyl group, a diphenylcarbazole-9-yl group, a phenylcarbazol-9-yl group, a phenyltriazinyl group, a biphenylyltriazinyl group, diphenyltriazinyl group, a phenyldibenzofuranyl group, a phenyldibenzothiophenyl group, an indiocarbazolyl group, a pyrazinyl group, a pyridazinyl group, a quinazolinyl group, a cinnolinyl group, a phthalazinyl group, a quinoxalinyl group, a pyrrolyl group, an indolyl group, a pyrrolo[3,2,1-jk]carbazolyl group, a furanyl group, a benzofuranyl group, a thiophenyl group, a benzothiophenyl group, a pyrazolyl group, an imidazolyl group, a benzimidazolyl group, a triazolyl group, an oxazolyl group, a benzoxazolyl group, a thiazolyl group, a benzothiazolyl group, an isothiazolyl group, a benzisothiazolyl group, a thiadiazolyl group, an isoxazolyl group, a benzisoxazolyl group, a pyrrolidinyl group, a piperidinyl group, a piperazinyl group, an imidazolidinyl group, an indro[3,2,1-jk]carbazolyl group, a dibenzothiophenyl group, or the like.

The dibenzofuranyl group and the dibenzothiophenyl group as described above are specifically any group described below, unless otherwise specified.

In the formulas (XY-76) to (XY-79), X_(B) is an oxygen atom or a sulfur atom.

The substituted or unsubstituted alkyl group described herein is, unless otherwise specified, preferably a methyl group, an ethyl group, a propyl group, an isopropyl group, a n-butyl group, an isobutyl group, a t-butyl group, or the like.

The “substituted or unsubstituted arylene group” descried herein refers to a group in which the above-described “aryl group” is converted into divalence, unless otherwise specified. Specific examples (specific example group G12) of the “substituted or unsubstituted arylene group” include a group in which the “aryl group” described in the specific example group G1 is converted into divalence. Namely, specific examples (specific example group G12) of the “substituted or unsubstituted arylene group” refer to a group derived from the “aryl group” described in specific example group G1 by removal of one hydrogen atom bonded to the ring carbon atoms thereof.

Specific examples (specific example group G13) of the “substituted or unsubstituted divalent heterocyclic group” include a group in which the “heterocyclic group” described in the specific example group G2 is converted into divalence. Namely, specific examples (specific example group G13) of the “substituted or unsubstituted divalent heterocyclic group” refer to a group derived from the “heterocyclic group” described in specific example group G2 by removal of one hydrogen atom bonded to the ring atoms thereof.

Specific examples (specific example group G14) of the “substituted or unsubstituted alkylene group” include a group in which the “alkyl group” described in the specific example group G3 is converted into divalence. Namely, specific examples (specific example group G14) of the “substituted or unsubstituted alkylene group” refer to a group derived from the “alkyl group” described in specific example group G3 by removal of one hydrogen atom bonded to the carbon atoms constituting the alkane structure thereof.

The substituted or unsubstituted arylene group described herein is any group described below, unless otherwise specified.

In the formulas (XY-20) to (XY-29), (XY-83) and (XY-84), R₉₀₈ is a substituent.

Then, m901 is an integer of 0 to 4, and when m901 is 2 or more, a plurality of R₉₀₈ may be the same with or different from each other.

In the formulas (XY-30) to (XY-40), R₉₀₉ is independently a hydrogen atom or a substituent. Two of R₉₀₉ may be bonded with each other through a single bond to form a ring.

In the formulas (XY-41) to (XY-46), R₉₁₀ is a substituent.

Then, m902 is an integer of 0 to 6. When m902 is 2 or more, a plurality of R₉₁₀ may be the same with or different from each other.

The substituted or unsubstituted divalent heterocyclic group described herein is preferably any group described below, unless otherwise specified.

In the formulas (XY-50) to (XY-60), R₉₁₁ is a hydrogen atom or a substituent.

In the formulas (XY-65) to (XY-75), X_(B) is an oxygen atom or a sulfur atom.

Herein, a case where “one or more sets of two or more groups adjacent to each other are bonded with each other to form a substituted or unsubstituted and saturated or unsaturated ring” will be described by taking, as an example, a case of an anthracene compound represented by the following formula (XY-80) in which a mother skeleton is an anthracene ring.

For example, two adjacent to each other into one set when “one or more sets of two or more groups adjacent to each other are bonded with each other to form the ring” among R₉₂₁ to R₉₃₀ include R₉₂₁ and R₉₂₂, R₉₂₂ and R₉₂₃, R₉₂₃ and Raw, R₉₂₄ and R₉₃₀, R₉₃₀ and R₉₂₅, R₉₂₅ and R₉₂₆, R₉₂₆ and R₉₂₇, R₉₂₇ and R₉₂₈, R₉₂₈ and R₉₂₉, and R₉₂₉ and R₉₂₁.

The above-described “one or more sets” means that two or more sets of two groups adjacent to each other may simultaneously form the ring. For example, a case where R₉₂₁ and R₉₂₂ are bonded with each other to form a ring A, and simultaneously R₉₂₅ and R₉₂₆ are bonded with each other to form a ring B is represented by the following formula (XY-81).

A case where “two or more groups adjacent to each other” form a ring means that, for example, R₉₂₁ and R₉₂₂ are bonded with each other to form a ring A, and R₉₂₂ and R₉₂₃ are bonded with each other to form a ring C. A case where the ring A and ring C sharing R₉₂₂ are formed, in which the ring A and the ring C are fused to the anthracene mother skeleton by three of R₉₂₁ to R₉₂₃ adjacent to each other, is represented by the following (XY-82).

The rings A to C formed in the formulas (XY-81) and (XY-82) are a saturated or unsaturated ring.

A term “unsaturated ring” means an aromatic hydrocarbon ring or an aromatic heterocyclic ring. A term “saturated ring” means an aliphatic hydrocarbon ring or an aliphatic heterocyclic ring.

For example, the ring A formed by R₉₂₁ and R₉₂₂ being bonded with each other, represented by the formula (XY-81), means a ring formed by a carbon atom of the anthracene skeleton bonded with R₉₂₁, a carbon atom of the anthracene skeleton bonded with R₉₂₂, and one or more arbitrary elements. Specific examples include, when the ring A is formed by R₉₂₁ and R₉₂₂, a case where an unsaturated ring is formed of a carbon atom of an anthracene skeleton bonded with R₉₂₁, a carbon atom of the anthracene skeleton bonded with R₉₂₂, and four carbon atoms, in which a ring formed by R₉₂₁ and R₉₂₂ is formed into a benzene ring. Further, when a saturated ring is formed, the ring is formed into a cyclohexane ring.

Here, “arbitrary elements” are preferably a C element, a N element, an O element and a S element. In the arbitrary elements (for example, a case of the C element or the N element), the bond(s) that is(are) not involved in the formation of the ring may be terminated by a hydrogen atom, or may be substituted by an arbitrary substituent. When the ring contains the arbitrary elements other than the C element, the ring to be formed is a heterocyclic ring.

The number of “one or more arbitrary elements” forming the saturated or unsaturated ring is preferably 2 or more and 15 or less, more preferably 3 or more and 12 or less, and further preferably 3 or more and 5 or less.

As specific examples of the aromatic hydrocarbon ring, a structure in which the aryl group described in specific example group G1 is terminated with a hydrogen atom may be mentioned.

As specific examples of the aromatic heterocyclic ring, a structure in which the aromatic heterocyclic group described in specific example group G2 is terminated with a hydrogen atom may be mentioned.

As specific examples of the aliphatic hydrocarbon ring, a structure in which the cycloalkyl group described in specific example group G6 is terminated with a hydrogen atom may be mentioned.

When the above-described “saturated or unsaturated ring” has a substituent, the substituent is an “arbitrary substituent” as described below, for example. When the above-mentioned “saturated or unsaturated ring” has a substituent, specie examples of the substituent refer to the substituents described in above-mentioned “the substituent described herein”.

In one embodiment of the present specification, the substituent (hereinafter, referred to as an “arbitrary substituent” in several cases) in the case of the “substituted or unsubstituted” is a group selected from the group consisting of

an unsubstituted alkyl group having 1 to 50 carbon atoms, an unsubstituted alkenyl group having 2 to 50 carbon atoms, an unsubstituted alkynyl group having 2 to 50 carbon atoms, an unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅)

—N(R₉₀₆)(R₉₀₇) wherein, R₉₀₁ to R₉₀₇ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and when two or more of Ran to R₉₀₇ exist, two or more of R₉₀₁ to R₉₀₇ may be the same with or different from each other, a halogen atom, a cyano group, a nitro group, an unsubstituted aryl group having 6 to 50 ring carbon atoms, and an unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment the substituent in the case of “substituted or unsubstituted” is a group selected from the group consisting of

an alkyl group having 1 to 50 carbon atoms, an aryl group having 6 to 50 ring carbon atoms, and a monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment the substituent in the case of “substituted or unsubstituted” is a group selected from the group consisting of

an alkyl group having 1 to 18 carbon atoms, an aryl group having 6 to 18 ring carbon atoms, and a monovalent heterocyclic group having 5 to 18 ring atoms.

Specific examples of each group of the arbitrary substituent described above are as described above.

Herein, unless otherwise specified, the saturated or unsaturated ring (preferably substituted or unsubstituted and saturated or unsaturated five-membered or six-membered ring, more preferably a benzene ring) may be formed by the arbitrary substituents adjacent to each other. Herein, unless otherwise specified, the arbitrary substituent may further have the substituent. Specific examples of the substituent that the arbitrary substituent further has include to the ones same as the arbitrary substituent described above.

[Organic EL Device]

The organic EL device according to one aspect of the invention comprises a cathode, an anode and an emitting layer disposed between the cathode and the anode, and it is characterized in that the emitting layer comprises a compound represented by the following formula (1) and one or more compounds selected from the group consisting of compounds represented by each of formulas (11), (21), (31), (41), (51), (61), (71) and (81).

Each compound is described later.

The organic EL device according to one aspect of the invention exhibits high device performance by possessing the above-mentioned constitution. Specifically, it is possible to provide an organic EL device with longer life.

According to one aspect of the present invention, a method for improving a performance of an organic EL device can also be provided, the method is characterized in that the compound represented by the formula (1) and one or more compounds selected from the group consisting of the formulas (11) to (81) are used in combination in the emitting layer of the organic EL device. Specifically, the method can improve an organic EL device performance as compared with the case where a compound having the same structure as formula (1) except that only protium atoms are contained as hydrogen atoms (hereinafter also referred to as “protium compound”) is used as a host material. The case where the protium compound is used means that a host material in an emitting layer consists essentially of the protium compound (the ratio of the protium compound to the sum of the protium compound and the compound represented by formula (1) is 90 mol % or more, 95 mol % or more, or 99 mol % or more).

That is, it is possible to increase a performance of an organic EL device by, instead of a protium compound or in addition to a protium compound, using a compound obtained by replacing at least one protium atoms on an anthracene skeleton of the protium compound with a deuterium atom (a compound represented by formula (1)) as a host material.

A schematic outline of the organic EL device of one aspect of the invention is explained by reference to the FIGURE.

The organic EL device 1 according to one aspect of the invention comprises substrate 2, anode 3, emitting layer 5, cathode 10, organic layer 4 disposed between the anode 3 and the emitting layer 5, and organic layer 6 disposed between the emitting layer 5 and the cathode 10.

The compound represented by the formula (1) and one or more compounds selected from a group consisting of compounds represented by each of formula (11), (21), (31), (41), (51), (61), (71) and (81) are contained in emitting layer 5 disposed between the anode 3 and the cathode 10. Each compound contained in the emitting layer 5 may be used singly or in combination of two or more.

(Compound Represented by Formula (1))

The compound represented by the formula (1) is explained below.

In the formula (1),

R₁ to R₈ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

when two or more of R₉₀₁ to R₉₀₇ exist, two or more of R₉₀₁ to R₉₀₇ may be the same with or different from each other;

at least one of R₁ to R_(a) is a deuterium atom;

two or more adjacent groups of R₁ to R₄ and two or more adjacent groups of R₅ to R₈ do not form a ring;

L₁ and L₂ are independently

a single bond, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms;

Ar is

a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

one of R₁₁ to R₁₈ is a single bond bonding to L₂;

R₁₁ to R₁₈ which are not single bonds bonding to L₂ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in R₁ to R₈; and

two or more adjacent groups of R₁₁ to R₁₈ do not form a ring.)

All of R₁ to R₈ may be deuterium atoms or a part of them (e.g., one or two of R₁ to R₈) may be deuterium atoms.

R₁ to R₈ that are not deuterium atoms are preferably hydrogen atoms (protium atoms).

In one embodiment, at least one hydrogen atom contained in one or more groups selected from a group consisting of L₁ and L₂ is a deuterium atom. In more detail, in one embodiment, one or more groups selected from the group consisting of L₁ and L₂ are an unsubstituted arylene group having 6 to 30 ring carbon atoms in which at least one hydrogen atom is a deuterium atom, or an unsubstituted divalent heterocyclic group having 5 to 30 ring atoms in which at least one hydrogen atom is a deuterium atom.

In one embodiment, L₁ and L₂ are independently a single bond, or a substituted or unsubstituted arylene group having 6 to 14 ring carbon atoms. It is preferable that at least one of L₁ and L₂ is a single bond.

In one embodiment, among R₁₁ to R₁₈, those which are not single bonds bonded to b are hydrogen atoms.

In one embodiment, at least one of R₁₁ to R₁₈ which is not a single bond bonding to b is a deuterium atom.

In one embodiment at least one hydrogen atom contained in one or more Ar is a deuterium atom. In more detail, in one embodiment, Ar is an unsubstituted aryl group having 6 to 50 ring carbon atoms in which at least one hydrogen atom is a deuterium atom, or an unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms in which at least one hydrogen atom is a deuterium atom.

Existence of a deuterium atom in the compound is confirmed by Mass Spectrometry or ¹H-NMR Spectrometry. The bonding position of a deuterium atom in the compound is identified by ¹H-NMR Spectrometry. In concrete terms, it is confirmed as follows.

If it is identified that, by Mass Spectrometry, a molecular weight of a target compound is greater by “one” than a molecular weight of a corresponding compound in which all hydrogen atoms are protium atoms, it is confirmed that one deuterium atom exists in the target compound. Further, the number of deuterium atoms in a molecule can be confirmed by an integration value obtained by ¹H-NMR analysis on the target compound, since no signal is observed by performing ¹H-NMR analysis on a deuterium atom. The bonding position of a deuterium can be identified by performing ¹H-NMR analysis on the target compound and assigning signals.

In the organic EL device according to one aspect of the invention, the content ratio of the protium compound to the total of the compound represented by formula (1) and the protium compound in the emitting layer is preferably 99 mol % or less. The content ratio of the protium compound is confirmed by Mass Spectrometry.

In one embodiment, the emitting layer of the organic EL device according to one aspect of the invention includes the compound represented by the formula (1) and a protium compound, and the content ratio of the former to the total thereof is 30 mol % or more, 50 mol % or more, 70 mol % or more, 90 mol % or more, 95 mol % or more, 99 mol % or more, or 100 mol %.

Ar is preferably a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, more preferably selected from groups represented by the following formulas (a1) to (a4).

wherein in the formulas (a1) to (a4),

* is a angle bond bonding to L₁;

R₂₁ is

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

m1 is an integer of 0 to 4;

m2 is an integer of 0 to 5;

m3 is an integer of 0 to 7;

when each of m1 to m3 is 2 or more, a plurality of R₂₁s may be the same or different; and

when each of m1 to m3 is 2 or more, adjacent R₂₁s are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring.

Preferably, L₁ and L₂ are independently a single bond, or a substituted or unsubstituted arylene group having 6 to 14 ring carbon atoms. It is preferable that at least one of L₁ and L₂ is a single bond.

In one embodiment, the compound represented by the formula (1) is a compound represented by following formula (2).

wherein in the formula (2), R₁ to R₈, Ar, L₁ and L₂ are as defined in the formula (1).

In one embodiment, the compound represented by the formula (1) is a compound represented by following formula (3).

wherein in the formula (3), Ar, L₁ and L₂ are as defined in the formula (1).

In one embodiment, the compound represented by the formula (1) is a compound represented by following formula (1A) or (1B).

wherein in the formula (1A) and (1B),

R_(1A) to R_(8A) are independently a hydrogen atom, and at least one of R_(1A) to R_(8A) is a deuterium atom;

L_(1A) and L_(2A) are independently a single bond, an unsubstituted phenylene group, or an unsubstituted naphthylene group;

Ar_(1A) is a substituted or unsubstituted phenyl group or a substituted or unsubstituted naphthyl group, and the substituent for Ar_(1A) is a phenyl group;

R_(11A) to R_(14A) are independently a hydrogen atom, or an unsubstituted aryl group including 6 to 50 ring carbon atoms; and

two or more adjacent groups of R_(11A) to R_(14A) do not form a ring.

In one embodiment, in the formula (1A) or (1B), at least two of R_(1A) to R_(1A) are deuterium atoms.

In one embodiment, in the formula (1A) or (1B), R_(1A) to R_(8A) are all deuterium atoms.

In one embodiment, in the formula (1A) or (1B), at least one hydrogen atom contained in Ar_(1A) is a deuterium atom.

In one embodiment, in the formula (1A) or (1B), R_(11A) to R_(14A) are hydrogen atoms.

In one embodiment, in the formula (1A) or (1B), R_(11A) to R_(14A) are deuterium atoms.

The compound represented by the formula (1) can be synthesized in accordance with the synthesis process described in Examples by using publicly known alternative reactions or materials corresponding to a target compound.

Examples of the compound represented by formula (1) include the following compounds.

(Compound Represented by Formula (11))

The compound represented by the formula (11) is explained below.

In the formula (11),

one or more pairs of two or more adjacent groups of R₁₀₁ to R₁₁₀ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

at least one of R₁₀₁ to R₁₁₀ is a monovalent group represented by the formula (12);

R₁₀₁ to R₁₁₀ that do not form the substituted or unsubstituted, saturated or unsaturated ring and that are not a monovalent group represented by the following formula (12) are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (12), Ar₁₀₁ and Ar₁₀₂ are independently

a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

L₁₀₁ to L₁₀₃ are independently

a single bonded, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms;

In the formula (11), it is preferable that two of R₁₀₁ to R₁₁₀ are the group represented by the formula (12).

In one embodiment, the compound represented by the formula (11) is represented by the following formula (13):

wherein in the formula (13), R₁₁₁ to R₁₁₈ are the same as R₁₀₁ to R₁₁₀ that is not a monovalent group represented by the formula (12) in the formula (11). Ar₁₀₁, Ar₁₀₂, L₁₀₁, L₁₀₂ and L₁₀₃ are as defined in the formula (12).

In the formula (11), L₁₀₁ is preferably a single bond and L₁₀₂ and L₁₀₃ are preferably a single bond.

In one embodiment, the compound represented by the formula (11) is represented by the formula (14) or (15).

wherein in the formula (14), R₁₁₁ to R₁₁₈ are as defined in the formula (13). Ar₁₀₁, Ar₁₀₂, L₁₀₂ and L₁₀₃ are as defined in the formula (12).

wherein in the formula (15), R₁₁₁ to R₁₁₈ are as defined in the formula (13). Ar₁₀₁ and Ar₁₀₂ are as defined in the formula (12).

In the formula (11) and formula (12), it is preferable that at least one of Ar₁₀₁ and Ar₁₀₂ is the group represented by the following formula (16).

wherein to the formula (16),

X₁₀₁ is an oxygen atom or a sulfur atom;

One or more pairs of two or more adjacent groups of R₁₂₁ to R₁₂₇ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring:

R₁₂₁ to R₁₂₇ that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₆),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

It is preferable that X₁₀₁ is an oxygen atom.

It is preferable that at least one of R₁₂₁ to R₁₂₇ is

a substituted or unsubstituted alky) group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

It is preferable that in the formula (11) and formula (12), Ar₁₀₁ is a group represented by the formula (16) and Ar₁₀₂ is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, the compound represented by the formula (11) is represented by the following formula (17).

wherein to the formula (17), R₁₁₁ to R₁₁₈ are as defined in the formula (13), and R₁₂₁ to R₁₂₇ are as defined in the formula (16);

R₁₃₁ to R₁₃₅ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and R₉₀₁ to R₉₀₇ are as defined in toe formula (1).

As the compound represented by the formula (11), the following compounds can be given as specific examples, for example. In the following example compounds, Me represents a methyl group.

(Compound Represented by Formula (21))

The compound represented by the formula (21) is explained below.

wherein, in the formula (21),

Zs are independently CR_(a) or N;

A1 ring and A2 ring are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

when a plurality of R_(a)s exist, one or more pairs of two or more adjacent groups of R_(a) are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

when a plurality of R_(b)s exist, one or more pairs of two or more adjacent groups of R_(b) are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

when a plurality of R_(c)s exist, one or more pairs of two or more adjacent groups of R_(c) are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

n21 and n22 are independently an integer of 0 to 4;

R_(a) to R_(c) that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1);

The “aromatic hydrocarbon ring” of A1 ring and A2 ring has the same structure as the compound obtained by introducing a hydrogen atom into the “aryl group” described above.

The “aromatic hydrocarbon ring” of the A1 ring and the A2 ring contains two carbon atoms in the fused bicyclic structure at the center of the formula (21) as ring atoms. Examples of “substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms” include compounds in which a hydrogen atom is introduced into the “aryl group” described in the example group G1.

The “heterocyclic ring” of A1 ring and A2 ring has the same structure as the compound obtained by introducing a hydrogen atom into toe “heterocyclic group” described above. The “heterocyclic ring” of the A1 ring and toe A2 ring contains two carbon atoms in the (used bicyclic structure at the center of the formula (21) as ring atoms. Examples of “substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms” include compounds in which a hydrogen atom is introduced into toe “heterocyclic group” described in the example group G2.

R_(b) is bonded to one of carbon atoms which form toe aromatic hydrocarbon ring of A1 ring, or one of atoms which form toe heterocycle of A1 ring.

R_(c) is bonded to one of carbon atoms which form the aromatic hydrocarbon ring of A2 ring, or one of atoms which form the heterocycle of A2 ring.

R_(c) is preferable that at least one (preferably two) of R_(a) to R_(c) is a group represented by the following formula (21a).

-L₂₀₁-Ar₂₀₁  (21a)

wherein to the formula (21a),

L₂₀₁ is

a single bond, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted bivalent heterocyclic group having 5 to 30 ring atoms;

Ar₂₀₁ is

a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms, or a group represented by toe following formula (21b):

wherein in the formula (21 b),

L₂₁₁ and L₂₁₂ are independently

a single bond, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms;

Ar₂₁₁ and Ar₂₁₂ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring; and

Ar₂₁₁ and Ar₂₁₂ that do not form a substituted or unsubstituted, saturated or unsaturated ring are independently

a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms or

a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms,

In one embodiment, the compound represented by the formula (21) is represented by foe following formula (22).

wherein in the formula (22),

one or more pairs of two or more adjacent groups of R₂₀₁ to R₂₁₁ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted saturated or unsaturated ring;

R₂₀₁ to R₂₁₁ that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₁), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1))

It is preferable that at least one (preferably two) of R₂₀₁ to R₂₁₁ is the group represented by the formula (21a). It is preferable that R₂₀₄ and R₂₁₁ are the group represented by the formula (21a).

In one embodiment, the compound represented by the formula (21) is a compound obtained by bonding the structure represented by the following formula (21-1) or (21-2) to A1 ring. In one embodiment, the compound represented by the formula (22) is a compound obtained by bonding the structure represented by the following formula (21-1) or (21-2) to the ring to which R₂₀₄ to R₂₀₇ bonds to.

wherein in the formula (21-1), two bonds shown by * independently bond to a ring carbon atom in the aromatic hydrocarbon ring or a ring atom in the heterocyclic group in A1 ring in the formula (21), or bond to one of R₂₀₄ to R₂₀₇ in the formula (22);

wherein in the formula (21-2), three bonds shown by * independently bond to a ring carbon atom in the aromatic hydrocarbon ring or a ring atom in the heterocyclic group in A1 ring in the formula (21), or bond to one of R₂₀₄ to R₂₀₇ in the formula (22);

One or more pairs of two or more adjacent groups of R₂₂₁ to R₂₂₇ and R₂₂₁ to R₂₃₉ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

R₂₂₁ to R₂₂₇ and R₂₃₁ to R₂₃₉ that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1)

In one embodiment, the compound represented by the formula (21) is a compound represented by the following formula (21-3), (21-4), or (21-5).

wherein in the formulas (21-3), (21-4) and (21-5),

A1 ring is as defined in the formula (21);

R₂₄₀₁ to R₂₄₀₇ are the same as R₂₂₁ to R₂₂₇ in the formulas (21-1) and (21-2);

R₂₄₁₀ to R₂₄₁₇ are the same as R₂₀₁ to R₂₁₁ in the formula (22); and the two R₂₄₁₇s may be the same or different.

In one embodiment, the substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms of A1 ring in the formula (21-5) is a substituted or unsubstituted napthalene ring, or a substituted or unsubstituted fluorene ring.

In one embodiment, the substituted or unsubstituted heterocycle having 5 to 50 ring atoms of A1 ring in the formula (21-5) is a substituted or unsubstituted dibenzofuran ring, a substituted or unsubstituted carbazole ring, or a substituted or unsubstituted dibenzothiophene ring.

In one embodiment, the compound represented by the formula (21) or (22) is selected from foe group consisting of the compounds represented by the following formulas (21-6-1) to (21-6-7).

wherein in the formulas (21-6-1) to (21-6-7),

R₂₄₂₁ to R₂₄₂₇ are the same as R₂₂₁ to R₂₂₇ in the formulas (21-1) and (21-2);

R₂₄₃₀ to R₂₄₃₇ and R₂₄₄₁ to R₂₄₄₄ are the same as R₂₀₁ to R₂₁₁ in the formula (22);

X is O, NR₉₀₁, or C(R₉₀₂) (R₉₀₃); and

R₉₀₁ to R₉₀₃ are as defined in the formula (1).

In one embodiment, in the compound represented by the formula (22), one or more pairs of two or more adjacent groups of R₂₀₁ to R₂₁₁ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring. This embodiment is described in the following formula (25).

(Compound Represented by Formula (25))

The compound represented by the formula (25) is explained below.

wherein in the formula (25),

two or more pairs selected from a group consisting of R₂₅₁ and R₂₅₂, R₂₅₂ and R₂₅₃, R₂₅₃ and R₂₅₅, R₂₅₅ and R₂₅₆, R₂₅₆ and R₂₅₇, R₂₅₈ and R₂₅₉, R₂₅₉ and R₂₆₀, and R₂₆₀ and R₂₆₁ bond with each other to form a substituted or unsubstituted, saturated or unsaturated ring;

Provided that the pair of R₂₅₁ and R₂₅₂ and the pair of R₂₅₂ and R₂₅₃ do not form a ring simultaneously; the pair of R₂₅₄ and R₂₅₆ and the pair of R₂₅₅ and R₂₅₆ do not form a ring simultaneously; the pair of R₂₅₆ and R₂₅₆ and the pair of R₂₅₆ and R₂₅₇ do not form a ring simultaneously; the pair of R₂₅₈ and R₂₅₉ and the pair of R₂₅₉ and R₂₆₀ do not form a ring simultaneously; and the pair of R₂₅₉ and R₂₆₀ and the pair of R₂₆₀ and R₂₆₁ do not form a ring simultaneously;

When two or more rings are formed by R₂₅₁ to R₂₆₁, the rings may be the same or different;

R₂₅₁ to R₂₆₁ that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, or —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

In the formula (25), R_(n) and R_(n+1) (n is an integer selected from 251, 252, 254 to 256 and 258 to 260) bond with each other to form a substituted or unsubstituted, saturated or unsaturated ring together with two ring carbon atoms to which R_(n) and R_(n+1) bond with. The ring is preferably configured with atoms selected from C atom, O atom, S atom and N atom, and the number of atoms is preferably 3 to 7, more preferably 5 or 6.

The number of the above-described ring structures in the compound represented by the formula (25) is, for example, 2, 3 or 4. Two or more ring structures may exist in the same benzene ring of the main skeleton in the formula (25), or may exist in different benzene rings. For example, the compound has three ring structures, one ring structure may exist in each of the three benzene rings in the formula (25).

As the above-mentioned ring structure in the compound represented by the formula (25), structures represented by the following formulas (251) to (260) can be given, for example.

wherein in the formulas (251) to (257),

each of *1 and *2, *3 and *4, *5 and *6, *7 and *8, *9 and *10, *11 and *12, and * 13 and * 14 represents two ring carbon atoms to which R_(n) and R_(n+1) bond, and R_(n) may bond to either one of the two ring carbon atoms of *1 and *2, *3 and *4, *5 and *6, *7 and *8, *9 and *10, *11 and *12, and *13 and *14;

X₂₅₀₁ is C(R₂₅₁₂) (R₂₅₁₃), NR₂₅₁₄, O or S;

one or more pairs of two or more adjacent groups of R₂₅₀₁ to R₂₅₀₆ and R₂₅₁₂ to R₂₅₁₃ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted saturated or unsaturated ring; and

R₂₅₀₁ to R₂₅₁₄ that do not form a substituted or unsubstituted saturated or unsaturated ring are the same as R₂₅₁ to R₂₆₁.

wherein in the formulas (258) to (260),

each of * 1 and * 2, and * 3 and * 4 represents two ring carbon atoms to which R_(n) and R_(n+1) bond, and R_(n) may bond to either one of the two ring carbon atoms of * 1 and *2, or *3 and *4;

X₂₅₀₁ is C(R₂₅₁₂) (R₂₅₁₃), NR₂₅₁₄, O or S;

one or more pairs of two or more adjacent groups of R₂₅₁₅ to R₂₅₂₅ bond to each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted saturated or unsaturated ring; and

R₂₅₁₅ to R₂₅₂₁ and R₂₅₂₂ to R₂₅₂₅ that do not form a substituted or unsubstituted saturated or unsaturated ring are the same as R₂₅₁ to R₂₆₁.

In the formula (25), it is preferable that at least one of R₂₅₂, R₂₅₄, R₂₅₅, R₂₆₀ and R₂₆₁ (preferably at least one of R₂₅₂, R₂₅₅, and R₂₆₀, more preferably R₂₅₂) is a group which does not form a ring.

-   (i) Substituent in the case where the ring structure formed by R_(n)     and R_(n+1) has a substituent in the formula (25), -   (ii) R₂₅₁ to R₂₆₁ that do not form a ring structure in the formula     (25), and -   (iii) R₂₅₀₁ to R₂₅₁₄ and R₂₅₁₅ to R₂₅₂₅ in the formulas (251)     to (260) are preferably independently     a hydrogen atom,     a substituted or unsubstituted alkyl group having 1 to 50 carbon     atoms,     a substituted or unsubstituted alkenyl group having 2 to 50 carbon     atoms,     a substituted or unsubstituted alkynyl group having 2 to 50 carbon     atoms,     a substituted or unsubstituted cycloalkyl group having 3 to 50 ring     carbon atoms,     —N(R₉₀₆) (R₉₀₇),     a substituted or unsubstituted aryl group having 6 to 50 ring carbon     atoms,     a substituted or unsubstituted monovalent heterocyclic group having     5 to 50 ring atoms, or     a group selected from the following groups.

wherein in the formulas (261) to (264),

R_(d)s are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

X is C(R₉₀₁)(R₉₀₂), NR₉₀₃, O, or S;

R₉₀₁ to R₉₀₇ are as defined to the formula (1); and

p1 is independently an integer of 0 to 5, p2 is independently an integer of 0 to 4, p3 is an integer of 0 to 3, and p4 is an integer of 0 to 7.

In one embodiment, the compound represented by the formula (25) is represented by the following formulas (25-1) to (25-6).

wherein in the formulas (25-1) to (25-6), ring d to ring i are independently a substituted or unsubstituted, saturated or unsaturated ring; and R₂₅₁ to R₂₆₁ are the same as defined in the formula (25).

In one embodiment, the compound represented by the formula (25) is represented by the following formulas (25-7) to (25-12).

wherein in the formulas (25-7) to (25-12), ring d to ring f, ring k, and ring j are independently a substituted or unsubstituted, saturated or unsaturated ring; and R₂₅₁ to R₂₆₁ are the same as defined in the formula (25).

In one embodiment, toe compound represented by toe formula (25) is represented by the following formulas (25-13) to (25-21).

wherein in toe formulas (25-13) to (25-21), ring d to ring k are independently a substituted or unsubstituted, saturated or unsaturated ring; and R₂₅₁ to R₂₆₁ are the same as defined in the formula (25).

As a substituent in the case where toe ring g or ring h further has a substituent,

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a group represented by the formula (261), (263) or (264) can be given for example.

In one embodiment, the compound represented by toe formula (25) is represented by one of toe following formulas (25-22) to (25-25).

wherein in the formulas (25-22) to (25-25), X₂₅₀ is independently C(R₉₀₁)(R₉₀₂), NR₉₀₃, O or S;

R₂₅₁ to R₂₆₁, and R₂₇₁ to R₂₇₈ are the same as R₂₅₁ to R₂₆₁ in the formula (25); and R₉₀₁ to R₉₀₃ are as defined in the formula (1).

In one embodiment, the compound represented by the formula (25) is represented by the following formula (25-26).

wherein in the formula (25-26), X₂₅₀ is C(R₉₀₁)(R₉₀₂), NR₉₀₃, O or S; R₂₅₃, R₂₅₄, R₂₅₇, R₂₅₈, R₂₆₁, and R₂₇₁ to R₂₆₂ are the same as R₂₅₁ to R₂₆₁ in the formula (25); and R₉₀₁ to R₉₀₃ are as defined in the formula (1).

As the compound represented by the formula (21), the following compounds can be shown for example. In the following example compounds, Me represents methyl group.

(Compound Represented by Formula (31))

The compound represented by the formula (31) is explained below.

The compound represented by formula (31) is a compound corresponding to the compound represented by the formula (21-3).

wherein in the formula (31),

one or more pairs of two or more adjacent groups of R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₃₂₁ and R₃₂₂ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₆₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

Example of “One pair of two or more adjacent groups of R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇” is pairs of R₃₀₁ and R₃₀₂, R₃₀₂ and R₃₀₃ R₃₀₃ and R₃₀₄, R₃₀₅ and R₃₀₆, R₃₀₆ and R₃₀₇, and R₃₀₁, R₃₀₂ and R₃₀₃, and the like.

In one embodiment, at least one of R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇, preferably two of R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ is a group represented by —N(R₉₀₆)(R₉₀₇).

In one embodiment, R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ are independently a hydrogen atom, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, the compound represented by the formula (31) is a compound represented by the following formula (32).

wherein in the formula (32),

one or more pairs of two or more adjacent groups of R₃₃₁ to R₃₃₄ and R₃₄₁ to R₃₄₄ form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted saturated or unsaturated ring;

R₃₃₁ to R₃₃₄ and R₃₄₁ to R₃₄₄ that do not form the substituted or unsubstituted, saturated or unsaturated ring and R₃₅₁ and R₃₅₂ are independently

a hydrogen atom, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₃₆₁ to Raw are independently

a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, the compound represented by the formula (31) is a compound represented by the formula (33).

wherein in the formula (33), R₃₅₁, R₃₅₂, and R₃₆₁ to R₃₀₄ are as defined in the formula (32).

In one embodiment, the compound represented by the formula (31) is a compound represented by the formula (34) or (35).

wherein in the formulas (34) and (35),

R₃₆₁ to R₃₆₄ are as defined in the formula (32);

one or more pairs of two or more adjacent groups of R₃₇₁ to R₃₇₇ and R₃₈₀ to R₃₈₆ form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted saturated or unsaturated ring; and

R₃₇₁ to R₃₇₇ and R₃₈₀ to R₃₈₆ that do not form the substituted or unsubstituted, saturated or unsaturated ring and R₃₀₇ are independently

a hydrogen atom, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms, and two R₃₆₇s may be the same with or different from each other.

In one embodiment, fee compound represented by the formula (31) is a compound represented by the formula (34-2) or (35-2).

wherein in the formulas (34-2) and (35-2), R₃₆₁ to R₃₆₄, R₃₇₅ to R₃₇₇ and R₃₆₄ to R₃₆₇ are as defined in the formulas (34) and (35).

In one embodiment, R₃₆₁ to R₃₆₄ in the formulas (32), (33), (34), (35), (34-2) and (35-2) are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms (preferably a substituted or unsubstituted phenyl group).

In one embodiment, R₃₂₁ and R₃₂₂ in the formula (31) and R₃₅₁, R352 and R₃₈₇ in fee formulas (32), (33), (34), (35), (34-2) and (35-2) are independently a hydrogen atom or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms (preferably a substituted or unsubstituted phenyl group).

In one embodiment, fee compound represented by fee formula (31) is one or more compounds selected from fee group consisting of fee following formulas (32-11), (34-11) and (35-11).

wherein in the formulas (32-11), (34-11) and (35-11),

one or more pairs of two or more adjacent groups of R₃₃₀₁ to R₃₃₀₇ and R₃₃₁₁ to R₃₃₁₇ form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

R₃₃₀₁ to R₃₃₀₇ and R₃₃₁₁ to R₃₃₁₇ that do not form the substituted or unsubstituted, saturated or unsaturated ring, and R₃₃₃₁ are independently

a hydrogen atom, a substituted or unsubstituted aryl group having 6 to 20 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 20 ring atoms;

two R₃₃₃₁s may be the same with or different from each other; and

R₃₃₂₁ to R₃₃₂₄ are independently

a substituted or unsubstituted aryl group having 6 to 20 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 20 ring atoms.

In one embodiment, the one or more compounds selected from the group consisting of the formulas (32-11), (34-11) and (35-11) is one or more compounds selected from a group consisting of the following formulas (32-12), (34-12) and (35-12).

wherein in the formulas (32-12), (34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ and R₃₃₃₁ are as defined in the formulas (32-11), (34-11) and (35-11).

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12), (34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ are independently a substituted or unsubstituted phenyl group.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12), (34-12) and (35-12), two R₃₃₃₁s are independently a hydrogen atom.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12), (34-12) and (35-12), the substituent in the case of “substituted or unsubstituted” is selected from the group consisting of an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 ring carbon atoms, and a monovalent heterocyclic group having 5 to 20 ring atoms.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12), (34-12) and (35-12), the substituent in the case of “substituted or unsubstituted” is an alkyl group having 1 to 5 carbon atoms.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12), (34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ are independently a substituted or unsubstituted phenyl group, and two R₃₃₃₁s are independently a hydrogen atom.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12), (34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ are independently a substituted or unsubstituted phenyl group, two R₃₃₃₁s are independently a hydrogen atom, and the substituent in the case of “substituted or unsubstituted” is selected from the group consisting of an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 ring carbon atoms, and a monovalent heterocyclic group having 5 to 20 ring atoms.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12), (34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ are independently a substituted or unsubstituted phenyl group, two R₃₃₃₁s are independently a hydrogen atom, and the substituent in the case of “substituted or unsubstituted” is an alkyl group having 1 to 5 carbon atoms.

In one embodiment, in the compound represented by the formula (31), one or more pairs of two or more adjacent groups of Ran to R₃₀₇ and R₃₁₁ to R₃₁₇ form a substituted or unsubstituted, saturated or unsaturated ring.

In one embodiment, the compound represented by the formula (31) is one or more compounds selected from the group consisting of the following formulas (36-1) to (36-6).

wherein in the formulas (36-1) to (36-6),

one or more pairs of two or more adjacent groups of R₃₆₀₅ to R₃₆₀₇, R₃₆₁₅ to R₃₆₁₇ and R₃₆₃₁ bond with each other to form a substituted or unsubstituted, saturated or unsaturated ring or do not form the ring;

one or more pairs of two or more adjacent groups of R₃₆₀₁ to R₃₆₀₄, R₃₆₁₁ to R₃₆₁₄ and R₃₆₂₁ to R₃₆₂₈ bond with each other to form a substituted or unsubstituted, saturated or unsaturated ring or do not form the ring;

R₃₆₀₁ to R₃₆₀₇, R₃₆₁₁ to R₃₆₁₇, R₃₆₂₈ to R₃₆₂₈ and R₃₆₃₁ that do not form the ring are independently

a hydrogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

when two or more of R₉₀₁ to R₉₀₇ exist, two or more of R₉₀₁ to R₉₀₇ may be the same with or different from each other,

X₁ is selected from O, S and N(R₃₆₄₁), and two X₁s may be the same with or different from each other;

R₃₆₄₁ and one or more groups selected from R₃₆₀₁ to R₃₆₀₄, R₃₆₁₁ to R₃₆₁₄, R₃₆₂₄ and R₃₆₂₈ bond with each other to form a substituted or unsubstituted, saturated or unsaturated ring or do not form the ring; and

R₃₆₄₁ that do not form the ring is a hydrogen atom,

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, the compound represented by the formula (31) is a compound represented by the formula (36-1) or (36-2), In one embodiment, the compound represented by the formula (31) is a compound represented by the formula (36-1).

In one embodiment, in the compound represented by the formulas (36-1) to (36-6), two R₃₆₃₁s are phenyl groups.

In one embodiment, in the compound represented by the formulas (36-1) to (36-6), X₁ is N(R₃₆₄₁).

In one embodiment, in the compound represented by the formulas (36-1) to (36-6), R₃₆₄₁ is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, the compound represented by the formula (31) is a compound represented by the following formula (36-1-1).

wherein in the formula (36-1-1),

one or more pairs of two or more adjacent groups of R₃₀₀₁, R₃₀₀₂, R₃₀₀₅ to R₃₀₀₇, R₃₀₁₀, R₃₀₁₁, R₃₀₁₄ to R₃₀₁₆ and R₃₀₃₁ to R₃₀₃₄ bond with each other to form a substituted or unsubstituted, saturated or unsaturated ring or do not torn toe ring;

X_(a)s are independently selected from O, S and N(R₃₀₃₅);

R₃₀₃₅ and R₃₀₃₁ bond with each other to form a substituted or unsubstituted, saturated or unsaturated ring or do not form the ring; and

R₃₀₀₁, R₃₀₀₂, R₃₀₀₆ to R₃₀₀₇, R₃₀₁₀, R₃₀₁₁, R₃₀₁₄ to R₃₀₁₆ and R₃₀₃₁ to R₃₀₃₅ that do not form toe ring and R₃₀₂₁ and R₃₀₂₂ are independently

a hydrogen atom, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, a substituent in toe case of “substituted or unsubstituted” in toe formulas (31) to (35), (34-2), (35-2), (32-11), (34-11), (35-11), (32-12), (34-12), (35-12), (36-1) to (36-6) and (36-1-1) is a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,

a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

As the compound represented by the formula (31), the fallowing compounds can be given for example. In the following example compounds, Me represents methyl group.

(Compound Represented by Formula (41))

The compound represented by the formula (41) is explained below.

wherein, in the formula (41),

a ring, b ring and c ring are independently

a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

R₄₀₁ and R₄₀₂ are independently bonded to the a ring, the b ring or the c ring to form a substituted or unsubstituted heterocyclic ring or do not form a substituted or unsubstituted heterocyclic ring;

R₄₀₁ and R₄₀₂ that do not form the substituted or unsubstituted heterocyclic ring are independently

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

The a ring, b ring and c ring are rings (a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms) fuse to the fused bicyclic structure composed of B atom and two N atoms in the center of the formula (41).

The “aromatic hydrocarbon ring” of the a ring, the b ring and the c ring has the same structure as the compound obtained by introducing a hydrogen atom into the “aryl group” described above. The “aromatic hydrocarbon ring” of the a ring contains three carbon atoms in the fused bicyclic structure in the center of the formula (41) as ring atoms. The “aromatic hydrocarbon ring” of the b ring and the c ring contain two carbon atoms in the fused bicyclic structure in the center of the formula (41) as ring atoms. As examples of “substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms”, compounds in which a hydrogen atom is introduced into the “aryl group” described in the group G1 and the like can be given.

The “heterocyclic ring” of the a ring, the b ring and the c ring has the same structure as the compound obtained by introducing a hydrogen atom into the “heterocyclic group” described above. The “heterocyclic ring” of the a ring contains three carbon atoms in the fused bicyclic structure in the center of the formula (41) as ring atoms. The “heterocyclic ring” of the b ring and the c ring contain two carbon atoms in the fused bicyclic structure in the center of the formula (41) as ring atoms. As examples of “substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms”, compounds in which a hydrogen atom is introduced into the “heterocyclic group” described in the group G2.

R₄₀₁ and R₄₀₂ may be independently bonded to the a ring, the b ring or the c ring to form a substituted or unsubstituted heterocyclic ring. This heterocyclic ring contains the nitrogen atom in the fused bicyclic structure in the center of the formula (41). This heterocyclic ring may contain a heteroatom other than the nitrogen atom. “R₄₀₁ and R₄₀₂ are bonded to the a ring, the bring or the c ring” means, specifically, an atom forming the a ring, the bring or the c ring is bonded to an atom forming R₄₀₁ and R₄₀₂. For example, it is possible that R₄₀₁ is bonded to the a ring to form a nitrogen-containing heterocyclic ring having a two-ring fused structure (or three or more rings fused structure) in which a ring containing R₄₀₁ and the a ring are fused.

The same applies to the case where R₄₀₁ is bonded to the b ring, R₄₀₂ is bonded to the a ring, and R₄₀₂ is bonded to the c ring.

In one embodiment, the a ring, the b ring and the c ring in the formula (41) are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms.

In one embodiment the a ring, the b ring and the c ring in the formula (41) are independently a substituted or unsubstituted benzene ring or a substituted or unsubstituted naphthalene ring.

In one embodiment R₄₀₁ and R₄₀₂ in the formula (41) are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms, and preferably a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, the compound represented by the formula (41) is a compound represented by the following formula (42).

wherein in the formula (42),

R_(401A) is bonded with one or more groups selected from R₄₁₁ or R₄₂₁ to form a substituted or unsubstituted heterocyclic ring, or does not form a substituted or unsubstituted heterocyclic ring; R_(402A) is bonded with one or more group selected from R₄₁₃ or R₄₁₄ to form a substituted or unsubstituted heterocyclic ring, or does not form a substituted or unsubstituted heterocyclic ring;

R_(401A) and R_(402A) that do not form a substituted or unsubstituted heterocyclic ring are independently

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

One or more pairs of two or more adjacent groups of R₄₁₁ to R₄₂₁ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

R₄₁₁ to R₄₂₁ that do not form the substituted or unsubstituted heterocyclic ring or the substituted or unsubstituted, saturated or unsaturated ring are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

R_(401A) and R_(402A) in the formula (42) correspond to R₄₀₁ and R₄₀₂ in the formula (41).

R_(401A) and R₄₁₁ may be bonded with each other to form a nitrogen-containing heterocyclic ring having two-ring fused structure (or three or more rings fused structure) which is a fused ring of a ring containing R_(401A) and R₄₁₁ and the benzene ring of the a ring, for example. As examples of the nitrogen-containing heterocyclic ring, compounds correspond to nitrogen-containing heterocyclic group having two or more ring fused structure in the group G2 can be given. The same applies to the cases where R_(401A) and R₄₁₂ are bonded, R_(402A) and R₄₁₃ are bonded, and R_(402A) and R₄₁₄ are bonded.

One or more pairs of two or more adjacent groups of R₄₁₁ to R₄₂₁ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring. For example, R₄₁₁ and R₄₁₂ are bonded to form a benzene ring, an indole ring, a pyrrole ring, a benzofuran ring, a benzothiophene ring or the like which fuses to the six-membered ring to which R₄₁₁ and R₄₁₂ bond, and the formed fused ring is a naphthalene ring, a carbazole ring, an indole ring, a dibenzofuran ring or a dibenzothiophene ring.

In one embodiment, R₄₁₁ to R₄₂₁ that do not contribute to form a ring are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, R₄₁₁ to R₄₂₁ that do not contribute to form a ring are independently a hydrogen atom, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, R₄₁₁ to R₄₂₁ that do not contribute to form a ring are independently a hydrogen atom or a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, R₄₁₁ to R₄₂₁ that do not contribute to form a ring are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, and at least one of R₄₁₁ to R₄₂₁ is a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, toe compound represented by the formula (42) is a compound represented by toe following formula (43).

wherein in toe formula (43),

R₄₃₁ is bonded with R₄₄₆ to form a substituted or unsubstituted heterocyclic ring, or does not form a substituted or unsubstituted heterocyclic ring; R₄₃₃ is bonded with R₄₄₇ to form a substituted or unsubstituted heterocyclic ring, or does not form a substituted or unsubstituted heterocyclic ring; R₄₃₄ is bonded with R₄₅₁ to form a substituted or unsubstituted heterocyclic ring, or does not form a substituted or unsubstituted heterocyclic ring; R₄₄₁ is bonded with R₄₄₂ to form a substituted or unsubstituted heterocyclic ring, or does not form a substituted or unsubstituted heterocyclic ring;

One or more pairs of two or more adjacent groups of R₄₃₁ to R₄₅₁ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

R₄₃₁ to R₄₅₁ that do not form a substituted or unsubstituted heterocyclic ring are independently a hydrogen atom,

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

R₄₃₁ may bond to R₄₄₆ to form a substituted or unsubstituted heterocyclic ring. For example, R₄₃₁ may bonds with R₄₄₆ form a nitrogen-containing heterocyclic ring with three or more fused rings of the benzene ring to which R₄₆ bond, a nitrogen-containing ring and the benzene ring of the a ring. As examples of the nitrogen-containing heterocyclic ring, compounds correspond to nitrogen-containing heterocyclic group having three or more ring fused structure in the group G2 can be given. The same applies to the cases where R₄₃₃ and R₄₄₇ are bonded, R₄₃₄ and R₄₅₁ are bonded, and R₄₄₁ and R₄₄₂ are bonded.

In one embodiment, R₄₃₁ to R451 that do not contribute to form a ring are independently, a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, R₄₃₁ to R451 that do not contribute to form a ring are independently, a hydrogen atom, a substituted or unsubstituted aryl group having 6 to 50 carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, R₄₃₁ to R451 that do not contribute to form a ring are independently a hydrogen atom or a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, R₄₃₁ to R451 that do not contribute to form a ring are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, and at least one of R₄₃₁ to R451 is a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, the compound represented by the formula (43) is a compound represented by the following formula (43A).

wherein in the formula (43A),

R₄₆₁ is

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; and

R₄₆₂ to R465 are independently

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, R₄₆₁ to R465 are independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, R₄₆₁ and R465 are independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, the compound represented by the formula (43) is a compound represented by the following formula (43B).

wherein in the formula (43B),

R₄₇₁ and R₄₇₂ are independently,

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —N(R₉₀₆) (R₉₀₇), or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms;

R₄₇₃ to R₄₇₅ are independently,

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —N(R₉₀₆) (R₉₀₇), or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; and

R₉₀₆ and R₉₀₇ are as defined in the formula (1).

In one embodiment, the compound represented by the formula (43) is the compound represented by the following formula (43B′).

wherein in the formula (43B′), R₄₇₂ to R₄₇₅ are as defined in the formula (43B).

In one embodiment, at least one of R₄₇₁ to R₄₇₅ is

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —N(R₉₀₆) (R₉₀₇), or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment,

R₄₇₂ is

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, —N(R₉₀₆) (R₉₀₇), or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; and

R₄₇₁ and R₄₇₃ to R₄₇₅ are independently

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, —N(R₉₀₆) (R₉₀₇), or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, the compound represented by the formula (43) is a compound represented by the formula (43C).

wherein in the formula (43C),

R₄₈₁ and R₄₈₂ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; and

R₄₈₃ to R₄₈₆ are independently

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, the compound represented by the formula (43) is the compound represented by the following formula (43C′).

wherein in the formula (43C′), R₄₈₃ to R₄₈₆ are as defined in the formula (43C).

In one embodiment, R₄₈₁ to R₄₈₆ are independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, R₄₈₁ to R₄₈₆ are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, the compound represented by the formula (43) is the compound represented by the following formula (43D).

wherein in the formula (43D),

R₄₆₁₁ is a hydrogen atom, an unsubstituted alkyl group including 1 to 6 carbon atoms, an unsubstituted cycloalkyl group including 3 to 10 ring carbon atoms, —Si(R₉₁₁)(R₉₁₂)(R₉₁₃), or —N(R₉₁₄)(R₉₁₅);

R₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl group including 1 to 6 carbon atoms, an unsubstituted cycloalkyl group including 3 to 10 ring carbon atoms, or —Si(R₉₁₁)(R₉₁₂)(R₉₁₃);

R₉₁₁ to R₉₁₃ are independently an unsubstituted alkyl group including 1 to 6 carbon atoms or an unsubstituted aryl group including 6 to 18 ring carbon atoms;

R₉₁₄ to R₉₁₅ are independently an unsubstituted aryl group including 6 to 18 ring carbon atoms.

In one embodiment, in the formula (43D), Roan is a hydrogen atom, an unsubstituted alkyl group including 1 to 6 carbon atoms, or —N(R₉₁₄)(R₉₁₅).

In one embodiment, in the formula (43D), R₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl group including 1 to 6 carbon atoms, or an unsubstituted cycloalkyl group including 3 to 10 ring carbon atoms.

In one embodiment, in the formula (43D), R₄₆₁₁ is —N(R₉₁₄)(R₉₁₅), and R₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl group including 1 to 6 carbon atoms.

In one embodiment in the formula (43D), R₄₆₁₁ is an unsubstituted alkyl group including 1 to 6 carbon atoms, and R₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl group including 1 to 6 carbon atoms.

In one embodiment in the formula (43D), R₄₆₁₁ is a hydrogen atom, and R₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl group including 1 to 6 carbon atoms, or an unsubstituted cycloalkyl group inducing 3 to 10 ring carbon atoms.

In one embodiment, in the formula (43D), at least one of the hydrogen atoms included in one or more selected from the group consisting of R₉₁₄ and R₉₁₅ is a deuterium atom.

The compound represented by the formula (41) can be synthesized by the following method: An intermediate is obtained by bonding the a ring, the b ring and the c ring with linking groups (a group containing N—R₁ and a group containing N—R₂) (first reaction), and a final compound is obtained by bonding the a ring, the b ring and the c ring with a linking group (a group containing B) (second reaction). In the first reaction, an amination reaction such as Buchwald-Hartwig reaction can be applied. In the second reaction, tandem hetero-Friedel-Crafts reaction or the like can be applied.

Examples of the compound represented by the formula (41) are described below. They are just exemplified compounds and the compound represented by the formula (41) is not limited to the following examples. In the following example compounds, Me represents methyl group, and tBu represents tert-butyl group.

(Compound Represented by Formula (51))

The compound represented by the formula (51) is explained below.

wherein, in the formula (51),

r ring is a ring represented by the formula (52) or formula (53) which is fused to an adjacent ring at an arbitrary position;

q ring and s ring are independently a ring represented by the formula (54) which is fused to an adjacent ring at an arbitrary position;

p ring and t ring are independently a ring represented by the formula (55) or the formula (56) which is fused to an adjacent ring at an arbitrary position;

when a plurality of R₅₀₁s exist, adjacent Rans are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;

X₅₀₁ is an oxygen atom, a sulfur atom, or NR₅₀₂;

R₅₀₁ and R₅₀₂ that do not form the substituted or unsubstituted saturated or unsaturated ring are a hydrogen atom,

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

Ar₅₀₁ and Ar₅₀₂ are independently

a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

L₅₀₁ is

a substituted or unsubstituted alkylene group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenylene group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynylene group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkylene group having 3 to 50 ring carbon atoms, a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 50 ring atoms;

m1 is independently an integer of 0 to 2, m2 is independently an integer of 0 to 4, m3s are independently an integer of 0 to 3, and m4s are independently an integer of 0 to 5; when a plurality of R₃₀₁s exist, R₅₀₁s may be the same or different;

In the formula (51), each of the p ring to the t ring is fused to an adjacent ring by sharing two carbon atoms. The position and direction of fusing are not limited, and condensation is possible at any position and direction.

In one embodiment, in the formula (52) or (53) of the r ring, R₅₀₁ is a hydrogen atom.

In one embodiment, the compound represented by the formula (51) is represented by any one of the following formulas (51-1) to (51-6).

wherein in the formulas (51-1) to (51-6), R₅₀₁, X₅₀₁, Ar₅₀₁, Ar₅₀₂, L₅₀₁, m1 and m3 are as defined in the formula (51).

In one embodiment, the compound represented by the formula (51) is represented by any one of the following formulas (51-11) to (51-13).

wherein in the formulas (51-11) to (51-13), R₅₀₁, X₅₀₁, Ar₅₀₁, Ar₅₀₂, L₅₀₁, m1, m3 and m4 are as defined in the formula (51).

In one embodiment, the compound represented by the formula (51) is represented by any one of the following formulas (51-21) to (51-25).

wherein in the formulas (51-21) to (51-25), R₅₀₁, X₅₀₁, Ar₅₀₁, Ar₅₀₂, L₅₀₁, m1 and m4 are as defined in the formula (51).

In one embodiment, the compound represented by the formula (51) is represented by any one of the following formulas (51-31) to (51-33).

wherein in the formulas (51-31) to (51-33), R₅₀₁, X₅₀₁, Ar₅₀₁, Ar₅₀₂, L₅₀₁, m2 to m4 are as defined in the formula (51).

In one embodiment, Ar₅₀₁ and Ar₅₀₂ are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, one of Ar₅₀₁ and Ar₅₀₂ is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms and toe other is a substituted or unsubstituted monovalent heterocyclic ring having 5 to 50 ring atoms.

As examples of toe compound represented by the formula (51), toe following compounds can be given, for example. In the following example compounds, Me represents methyl group.

(Compound Represented by Formula (61))

The compound represented by the formula (61) is explained below.

wherein, in the formula (61),

at least one pair of R₆₀₁ and R₆₀₂, R₆₀₂ and R₆₀₃, and R₆₀₃ and R₆₀₄ are bonded with each other to form a divalent group represented by the formula (62);

at least one pair of R₆₀₅ and R₆₀₆, R₆₀₆ and R₆₀₇, and R₆₀₇ and R₆₀₈ are bonded with each other to form a divalent group represented by formula (63);

at least one of R₆₀₁ to R₆₀₄ that does not form the divalent group represented by the formula (62), and R₆₁₁ to R₆₁₄ is a monovalent group represented by the following formula (64);

at least one of R₈₀₅ to R₈₀₈ that do not form the divalent group represented by the formula (63), and R₆₂₁ to R₆₂₄ is a monovalent group represented by the following formula (64);

X₈₀₁ is an oxygen atom, a sulfur atom, or NR₈₀₉;

R₆₀₁ to R₆₀₈ that do not form the divalent group represented by the formulas (62) and (63) and that is not the monovalent group represented by the formula (64), R₆₁₁ to R₆₁₄ and R₆₂₁ to R₆₂₄ that are not the monovalent group represented by the formula (64), and R₆₀₉ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (64), Ar₆₀₁ and Ar₆₀₂ are independently

a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

L₆₀₁ to L₆₀₃ are independently

a single bonded, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms, or a divalent linking group formed by bonding 2 to 4 above mentioned groups;

In the formula (61), positions at which the divalent group represented by the formula (62) and the divalent group represented by the formula (63) are formed are not limited, and said groups can be formed at possible positions in R₆₀₁ to R₆₀₈.

In one embodiment, the compound represented by the formula (61) is represented by any one of the following formulas (61-1) to (61-6).

wherein in the formulas (61-1) to (61-6), Xan is as defined in the formula (61);

at least two of Rem to R₆₂₄ are monovalent groups represented by the formula (64);

R₆₀₁ to R₆₂₄ that are not monovalent groups represented by the formula (64) are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted a unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

In one embodiment, the compound represented by the formula (61) is represented by any one of the following formulas (61-7) to (61-18).

wherein in the formulas (61-7) to (61-18), X₆₀₁ is as defined in the formula (61); * is a single bond bonding to the monovalent group represented by the formula (64); and R₆₀₁ to R₆₂₄ are the sane as Rem to R₆₂₄ that are not monovalent groups represented by the formula (64).

R₆₀₁ to R₆₀₈ which do not form the divalent group represented by the formula (62) and (63) and are not monovalent groups represented by the formula (64), and R₆₁₁ to R₆₁₄ and R₆₂₁ to R₆₂₄ which are not monovalent groups represented by the formula (64) are preferably independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

The monovalent group represented by the formula (64) is preferably represented by the following formulas (65) or (66).

wherein in the formula (65), R₆₃₁ to R₆₄₀ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

wherein in the formula (66), Ar₆₀₁, L₆₀₁ and L₆₀₃ are as defined in the formula (64); and HAr₆₀₁ is a structure represented by the following formula (67);

wherein in the formula (67) X₆₀₂ is an oxygen atom or a sulfur atom;

any one of R₆₄₁ to R₆₄₈ is a single bond bonding to L₈₀₃;

R₆₄₁ to R₆₄₈ which are not single bonds are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃).

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).)

As specific example of toe compound represented by the formula (61), in addition to toe compounds described in WO2014/104144, the following compounds can be given, for example. In the following example compounds. Me represents methyl group.

(Compound Represented by Formula (71))

The compound represented by the formula (71) is explained below.

wherein, in the formula (71),

A₇₀₁ ring and A₇₀₂ ring are independently

a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

One or more rings selected from the group consisting of A₇₀₁ ring and A₇₀₂ ring are bonded to the bond * of the structure represented by the following formula (72);

wherein, in the formula (72),

A₇₀₃ rings are independently

a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, a a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

X₇₀₁ is NR₇₀₃, C(R₇₀₄)(R₇₀₅), Si(R₇₀₆) (R₇₀₇), Ge(R₇₀₈)(R₇₀₉), O, S or Se;

R₇₀₁ and R₇₀₂ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring or do not form a substituted or unsubstituted saturated or unsaturated ring;

R₇₀₁ and R₇₀₂ that do not form the substituted or unsubstituted, saturated or unsaturated ring, and R₇₀₃ to R₇₀₉ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

One or more selected from the group consisting of A701 ring and A702 ring is bonded to * in the structure represented by the formula (72). That is, in one embodiment, the ring carbon atom of the aromatic hydrocarbon ring or the ring atom of the heterocyclic ring of A701 ring is bonded to * in the structure represented by the formula (72). In one embodiment, the ring carbon atom of the aromatic hydrocarbon ring or the ring atom of the heterocyclic ring of A702 ring is bonded to * in the structure represented by the formula (72).

In one embodiment the group represented by the formula (73) is bonded to one or both of A701 ring and A702 ring.

wherein in the formula (73), Ar₇₀₁ and Ar₇₀₂ are independently

a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and

L₇₀₁ to L₇₀₃ are independently

a single bonded, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms, or a divalent linking group formed by bonding 2 to 4 above mentioned groups.

In one embodiment, in addition to A₇₀₁ ring, the ring carbon atom of the aromatic hydrocarbon ring or the ring atom of the heterocyclic ring of Ar₇₀₂ ring is bonded to * in the structure represented by the formula (72). In this case, the structures represented by formula (72) may be the same or different.

In one embodiment, R₇₀₁ and R₇₀₂ are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, R₇₀₁ and R₇₀₂ are bonded with each other to form a fluorene structure.

In one embodiment, Ar₇₀₁ ring and Ar₇₀₂ ring are substituted or unsubstituted aromatic hydrocarbon rings having 6 to 50 ring carbon atoms, and they are substituted or unsubstituted benzene rings, for example.

In one embodiment, Ar₇₀₃ ring is a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, and it is a substituted or unsubstituted benzene ring, for example.

In one embodiment, X₇₀₁ is O or S.

As specific example of the compound represented by the formula (71), the following compounds can be given, for example. In the following example compounds, Me represents methyl group.

(Compound Represented by Formula (81))

The compound represented by the formula (81) is explained below.

wherein, in the formula (81),

A₈₀₁ ring is a ring represented by the formula (82) which is fused to an adjacent ring at an arbitrary position;

A₈₀₂ ring is a ring represented by the formula (83) which is fused to an adjacent ring at an arbitrary position;

two bonds * bond to A₈₀₃ ring at an arbitrary position;

X₈₀₁ and X₈₀₂ are independently C(R₈₀₃)(R₈₀₄), Si(R₈₀₅)(R₈₀₆), an oxygen atom, or a sulfur atom;

A₈₀₃ ring is a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms;

Ar₈₀₁ is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₈₀₁ to R₈₀₆ are independently

a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),

—O—(R₉₀₄), —S—(R₉₀₅),

—N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

m801 and m802 are independently an integer of 0 to 2; when these are 2, Rams or ROBS may be the same or different;

a801 is an integer of 0 to 2; when a801 is 0 or 1, the structure in the parentheses indicated by “3-a801” may be the same or different from each other; when a801 is 2, Ar₈₀₁s may be the same or different from each other.

In one embodiment, Ar₈₀₁ is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, Ar₈₀₃ ring is a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, and it is a substituted or unsubstituted benzene ring, a substituted or unsubstituted naphthalene ring, or a substituted or unsubstituted anthracene ring, for example.

In one embodiment, R₈₀₃ and R₈₀₄ are independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, a801 is 1.

As specific example of the compound represented by the formula (81), the following compounds can be given, for example.

Specific examples of the above groups are as described in [Definition] of this specification.

In the organic EL device according to one aspect of the invention, known materials and device configurations may be applied as long as the device includes a cathode, an anode, and an emitting layer disposed between the cathode and the anode, and the emitting layer includes a compound represented by the following formula (1) and one or more compounds selected from the group consisting of compounds represented by each of formulas (11), (21), (31), (41), (51), (61), (71) and (81) as described above, and as long as the effect of the invention is not impaired.

In one embodiment, the emitting layer contains one or more selected from the group consisting of a compound represented by the formula (1A) and a compound represented by the formula (1B), and a compound represented by the formula (43D).

In one embodiment, the compound represented by the formula (1A) or (1B) is one or more selected from the group consisting of the compound represented by the formula BH-1, BH-2, BH-3, and BH-5 to BH-17, and the compound represented by the formula (43D) is one or more selected from the group consisting of the compound represented by the formula BD-9, BD-10, BD-1 land BD-12.

A content of the compound represented by the formula (1) in the emitting layer is preferably 80 mass % or more and 99 mass % or less based on the total mass of the emitting layer.

A content of the one or more compounds selected from the group consisting of compounds represented by each of formulas (11), (21), (31), (41), (51), (61), (71) and (81) is preferably 1 mass % or more and 20 mass % or less based on a total mass of the emitting layer.

One embodiment of the organic EL device preferably has the hole-transporting layer between the anode and the emitting layer.

One embodiment of the organic EL device preferably has the electron-transporting layer between the cathode and the emitting layer.

Specific examples of a typified device configuration of the organic EL device of the invention include structures such as

(1) an anode/an emitting layer/a cathode, (2) an anode/a hole-injecting layer/an emitting layer/a cathode, (3) an anode/an emitting layer/an electron-injecting-transporting layer/a cathode, (4) an anode/a hole-injecting layer/an emitting layer/an electron-injecting-transporting layer/a cathode, (5) an anode/an organic semiconductor layer/an emitting layer/a cathode, (6) an anode/an organic semiconductor layer/an electron barrier layer/an emitting layer/a cathode, (7) an anode/an organic semiconductor layer/an emitting layer/an adhesion improving layer/a cathode, (8) an anode/a hole-injecting-transporting layer/an emitting layer/an electron-injecting-transporting layer /a cathode, (9) an anode/an insulating layer/an emitting layer/an insulating layer/a cathode, (10) an anode/an inorganic semiconductor layer/an insulating layer/an emitting layer/an insulating layer /a cathode, (11) an anode/an organic semiconductor layer/an insulating layer/an emitting layer/an insulating layer /a cathode, (12) an anode/an insulating layer/a hole-injecting-transporting layer/an emitting layer/an insulating layer /a cathode, and (13) an anode/an insulating layer/a hole-injecting-transporting layer/an emitting layer/an electron-injecting-transporting layer/a cathode.

Among the above-described structures, a configuration of (8) is preferably used, but the configuration is not limited thereto.

In this specification, the term “hole-injecting-transporting layer” herein means “at least one of the hole-injecting layer and the hole-transporting layer”, and the term “electron-injecting-transporting layer” herein means “at least one of the electron-injecting layer and the electron-transporting layer”.

Hereinbelow, an explanation will be made on elements and materials other than the above-mentioned compound constituting each layer that can be used in the organic EL device according to one aspect of the invention.

(Substrate)

The substrate is used as a supporting body of the emitting device. As the substrate, glass, quarts, plastic or the like can be used. Further, a flexible substrate may be used. The flexible substrate means a substrate that can be bent. For example, a plastic substrate made of polycarbonate or vinyl polychloride or the like can be given.

(Anode)

In an anode formed on a substrate, it is preferable to use a metal having a large work function (specifically, 4.0 eV or more), an alloy, an electric conductive compound, a mixture of these or the like. Specifically, indium oxide-tin oxide (ITO: Indium Tin Oxide), indium oxide-tin oxide containing silicon or silicon oxide, indium oxide-zinc oxide, tungsten oxide, indium oxide containing zinc oxide, graphene, or the like can be given. In addition, gold (Au), platinum (Pt) or a nitride of a metal material (e.g. titanium nitride) or the like can be given.

(Hole-Injecting Layer)

The hole-injecting layer is a layer containing a substance having a high hole-injecting property. As a substance having a high hole-injecting property, a substance selected from molybdenum oxide, titanium oxide, vanadium oxide, rhenium oxide, ruthenium oxide, chromium oxide, zirconium oxide, hafnium oxide, tantalum oxide, silver oxide, tungsten oxide, manganese oxide, an aromatic amine compound, a polymer compound (oligomer, dendrimer, polymer, etc.) or the like can also be used

(Hole-Transporting Layer)

The hole-transporting layer is a layer containing a substance having a high hole-transporting property. For the hole-transporting layer, aromatic amine compounds, carbazole derivatives, anthracene derivatives and the like can be used. Polymer compounds such as poly (N-vinylcarbazole) (abbreviation: PVK) and poly(4-vinyltriphenylamine) (abbreviation: PVTPA) can also be used. However, any substance other than these may be used as long as it is a substance having a higher transporting property for holes than electrons. Note that the layer containing a substance having a high hole-transporting property is not limited to a single layer, but may be a stacked body of two or more layers made of the above substances.

(Guest Material of the Emitting Layer)

The emitting layer is a layer that comprises a substance having high luminous property, and various materials can be used. For example, as the substance having high luminous property, a fluorescent compound that emits fluorescent light or a phosphorescent compound that emits phosphorescent light can be used. The fluorescent compound is a compound capable of emitting light from a singlet excited state and the phosphorescent compound is a compound capable of emitting light from a triplet excited state.

As a blue fluorescent material that can be used for the emitting layer, pyrene derivatives, styrylamine derivatives, chrysene derivatives, fluoranthene derivatives, fluorene derivatives, diamine derivatives, triarylamine derivatives and the like can be used. An aromatic amine derivative or the like can be used as a green fluorescent light-emitting material that can be used in the emitting layer. As a red fluorescent material which can be used in emitting layer, a tetracene derivative, a diamine derivative or the like can be used.

Metal complexes such as iridium complexes, osmium complexes, platinum complexes and the like are used as the blue phosphorescent material that can be used in the emitting layer. An iridium complex or the like is used as a green phosphorescent material that can be used in the emitting layer. Metal complexes such as iridium complexes, platinum complexes, terbium complexes, europium complexes and the like are used as red phosphorescent materials that can be used in the emitting layer.

(Host Material of Emitting Layer)

The emitting layer may have a structure in which the substance having high luminescent property (guest material) described above is dispersed in another substance (host material). Various materials other than the compound represented by the formula (1) (for example, the compound represented by the formula (1A) or (1B)) can be used as substances for dispersing substances with high luminescent properties, and it is preferable to use a material having a high lowest unoccupied molecular orbital level (LUMO level) and a low highest occupied molecular orbital level (HOMO level), rather than a material having a high luminous property.

As a substance (host material) for dispersing a substance having a high luminous property, 1) a metal complex such as an aluminum complex, a beryllium complex or a zinc complex, 2) a heterocyclic compound such as an oxadiazole derivative, a benzimidazole derivative, a phenanthroline derivative or the like, 3) a fused aromatic compound such as a carbazole derivative, an anthracene derivative, a phenanthrene derivative, a pyrene derivative or a chrysene derivative, and 4) an aromatic amine compound such as a triarylamine derivative or a fused polycyclic aromatic amine derivative are used.

(Electron-Transporting Layer)

The electron-transporting layer is a layer containing a substance having a high election-transporting property. For the electron-transporting layer, 1) a metal complex such as an aluminum complex, a beryllium complex, or a zinc complex 2) a heteroaromatic compound such as an imidazole derivative, a benzimidazole derivative, an azine derivative, a carbazole derivative or a phenanthroline derivative, and 3) a polymer compound can be used.

(Electron-Injecting Layer)

The electron-injection layer is a layer containing a substance having a high electron-injection property. For the electron-injection layer, alkali metals, alkaline earth metals or a compound thereof such as lithium (Li), ytterbium (Yb), lithium fluoride (LiF), cesium fluoride (CsF), calcium fluoride (CaF₂), metal complex compound such as 8-quinolinolato lithium (Liq), lithium oxide (LiOx) or the like can be used.

(Cathode)

It is preferable to use a metal, an alloy, an electrically conductive compound, a mixture thereof, or the like having a small work function (specifically, 3.8 eV or less) for the cathode. Specific examples of such cathode material include elements belonging to Group 1 or Group 2 of the periodic table of elements, that is, alkali metals such as lithium (Li) and cesium (Cs), alkaline earth metals such as magnesium (Mg), calcium (Ca), and strontium (Sr),

an alloy containing these metals (for example, MgAg and AlLi), a rare earth metal such as europium (Eu) and ytterbium (Yb), and an alloy containing a rare earth metal.

In the organic EL device according to one aspect of the invention, the method for forming each layer is not particularly restricted. A conventionally known forming method such as a vacuum deposition method, a spin coating method or tee like can be used. Each layer such as the emitting layer or the like can be formed by a vacuum deposition method, a molecular beam evaporation method (MBE method), or a known coating method such as a dipping method, a solution spin coating method, a casting method, a bar coating method, or the like, that uses a solution of a material forming each layer dissolved in a solvent

In the organic EL device according to one aspect of the invention, the thickness of each layer is not particularly restricted. In general, in order to suppress occurrence of defects such as pinholes and to suppress the applied voltage and to improve luminous efficiency, tee thickness is normally preferably in a range of several nm to 1 μm.

[Electronic Device]

The electronic device according to one aspect of tee invention is characterized in that it is provided with the organic EL device according to one aspect of tee invention.

Specific examples of tee electronic device includes a display element such as an organic EL panel module; a display such as a TV, a mobile phone or a PC; and emitting devices such as lightings and lights for automobiles or the like.

EXAMPLES

The invention will specifically be explained with the examples and tee comparative examples below, and shall not be limited to tee contents of the examples in any way.

Synthesis Example 1 [Synthesis of Compound BH-1] Synthesis of Intermediate 1

To 13.3 g (50.0 mmol) of 9-bromoanthracene-d9, 6.4 g (52.5 mmol) of phenylboronic add and 1.2 g (1.00 mmol) of Pd[PPh₃]₄, 75 ml of toluene, 75 ml of dimethoxyethane and 75 ml (150.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 10.9 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 1 as follows (yield: 83%).

Synthesis of Intermediate 2

5.3 g (20.0 mmol) of Intermediate 1 was solubilized in 120 ml of dichloromethane, and the resulting solution was dropped into the solution of 3.2 g (20.0 mmol) of bromine in 12 ml of dichloromethane at room temperature, followed by being stirred for one hour.

After completion of the reaction, the sample was transferred to a separating funnel and washed with 2M Na₂S₂O₃ aqueous solution. The organic phase was further washed with 10% Na₂CO₃, and thereafter with water, and the separated organic phase was dried with MgSO₄, followed by being filtered and concentrated.

The concentrated residue was dispersed in methanol (100 mL), and the precipitated crystal was dried to obtain 6.5 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 2 as follows (yield: 95%).

Synthesis of Compound BH-1

To 1.7 g (5.0 mmol) of Intermediate 2, 1.1 g (5.3 mmol) of dibenzofuran-2-boronic add and 0.1 g (0.1 mmol) of Pd[PPh₃]₄, 7.5 ml of toluene, 7.5 ml of dimethoxyethane and 7.5 ml (15.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 1.6 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-1 as follows (yield: 75%).

Synthesis Example 2 [Synthesis of Compound BH-2] Synthesis of Intermediate 3

To 13.3 g (50.0 mmol) of 9-bromoanthracene-d9, 9.0 g (52.5 mmol) of 1-naphthalene boronic add and 1.2 g (1.00 mmol) of Pd[PPh₃]₄, 75 ml of toluene, 75 ml of dimethoxyethane and 75 ml (150.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 13.3 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 3 as follows (yield: 85%).

Synthesis of Intermediate 4

6.3 g (20.0 mmol) of Intermediate 3 was solubilized in 120 ml of dichloromethane, and the resulting solution was dropped into the solution of 3.2 g (20.0 mmol) of bromine in 12 ml of dichloromethane at room temperature, followed by being stirred for one hour.

After completion of the reaction, the sample was transferred to a separating funnel and washed with 2M Na₂S₂O₃ aqueous solution. The organic phase was further washed with 10% Na₂CO₃, and thereafter with water three times. The organic phase was dried with MgSO₄, followed by being filtered and concentrated.

The concentrated residue was dispersed in methanol (100 mL), and the precipitated crystal was dried to obtain 7.5 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 4 as follows (yield: 96%).

Synthesis of Compound BH-2

To 2.0 g (5.0 mmol) of Intermediate 4, 1.1 g (5.3 mmol) of dibenzofuran-2-boronic add and 0.1 g (0.1 mmol) of Pd[PPh₃]₄, 7.5 ml of toluene, 7.5 ml of dimethoxyethane and 7.5 ml (15.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 1.7 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-2 as follows (yield: 70%).

Synthesis Example 3 [Synthesis of Compound BH-3]

Except that 1.1 g (5.3 mmol) of dibenzofuran-1-boronic add was used instead of dibenzofuran-2-boronic acid, the reaction was carried out in the same way as in the synthesis example 1, thereby obtaining 1.3 g of white crystal. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-3 as follows (yield: 62%).

Synthesis Example 4 [Synthesis of Compound BH-4]

Except feat 1.1 g (5.3 mmd) of dibenzofuran-4-boronic add was used instead of dibenzofuran-2-boronic acid, the reaction was carried out in the same way as in the synthesis example 1, thereby obtaining 1.2 g of white crystal. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-4 as follows (yield: 55%).

Synthesis Example 5 [Synthesis of Compound BH-5]

Except that 1.5 g (5.3 mmol) of 4-(2-dibenzofuranyl)phenyl boronic add was used instead of dibenzofuran-2-boronic add, the reaction was carried out in the same way as in the synthesis example 1, thereby obtaining 1.8 g of white crystal. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-5 as follows (yield: 71%).

Synthesis Example 6 [Synthesis of Compound BH-6]

Except that 1.5 g (5.3 mmd) of 4-(2-dibenzofuranyl)phenyl boronic add was used instead of dibenzofuran-2-boronic add, the reaction was carried out in the same way as in the synthesis example 2, thereby obtaining 2.0 g of white crystal By conducting FD-MS analysis, the resulting compound was identified as Compound BH-6 as follows (yield: 73%).

Synthesis Example 7 [Synthesis of Compound BH-7] Synthesis of Intermediate 5

To 13.3 g (50.0 mmol) of 9-bromoanthracene-d9, 10.4 g (52.5 mmol) of 4-biphenylboronic add and 1.2 g (1.00 mmol) of Pd[PPh₃]₄, 75 ml of toluene, 75 ml of dimethoxyethane and 75 ml (150.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 14.1 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 5 as follows (yield: 83%).

Synthesis of Intermediate 6

6.8 g (20.0 mmol) of Intermediate 5 was solubilized in 120 ml of dichloromethane, and the resulting solution was dropped into the solution of 3.2 g (20.0 mmol) of bromine in 12 ml of dichloromethane at room temperature, followed by being stirred for one hour.

After completion of the reaction, the sample was transferred to a separating funnel and washed with 2M Na₂S₂O₃ aqueous solution. The organic phase was further washed with 10% Na₂CO₃, and thereafter with water three times. The organic phase was dried with MgSO₄, followed by being filtered and concentrated.

The concentrated residue was dispersed in methanol (100 mL), and the precipitated crystal was dried to obtain 8.0 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 6 as follows (yield: 96%).

Synthesis of Compound BH-7

To 2.1 g (5.0 mmol) of Intermediate 6, 1.1 g (5.3 mmol) of dibenzofuran-2-boronic acid and 0.1 g (0.1 mmol) of Pd[PPh₃]₄, 7.5 ml of toluene, 7.5 ml of dimethoxyethane and 7.5 ml (15.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 1.6 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-7 as follows (yield: 64%).

Synthesis Example 8 [Synthesis of Compound BH-8] Synthesis of Intermediate 7

To 13.3 g (50.0 mmol) of 9-bromoanthracene-d9, 10.4 g (52.5 mmol) of 3-biphenylboronic add and 1.2 g (1.00 mmol) of Pd[PPh₃]₄, 75 ml of toluene, 75 ml of dimethoxyethane and 75 ml (150.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while storing for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 13.6 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 7 as follows (yield: 80%).

Synthesis of Intermediate 8

6.8 g (20.0 mmol) of Intermediate 7 was solubilized in 120 ml of dichloromethane, and the resulting solution was dropped into the solution of 3.2 g (20.0 mmol) of bromine in 12 ml of dichloromethane at room temperature, followed by being stirred for one hour.

After completion of the reaction, the sample was transferred to a separating funnel and washed with 2M Na₂S₂O₃ aqueous solution. The organic phase was further washed with 10% Na₂CO₃, and thereafter with water three times. The organic phase was dried with MgSO₄, followed by being filtered and concentrated.

The concentrated residue was dispersed in methanol (100 mL), and the precipitated crystal was dried to obtain 8.0 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 8 as follows (yield: 96%).

Synthesis of Compound BH-8

To 2.1 g (5.0 mmol) of Intermediate 8, 1.1 g (5.3 mmol) of dibenzofuran-2-boronic acid and 0.1 g (0.1 mmol) of Pd[PPh₃]₄, 7.5 ml of toluene, 7.5 ml of dimethoxyethane and 7.5 ml (15.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 1.5 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-8 as follows (yield: 59%).

Synthesis Example 9 [Synthesis of Compound BH-9] Synthesis of Intermediate 9

To 13.3 g (50.0 mmol) of 9-bromoanthracene-d9, 10.4 g (52.5 mmol) of 2-biphenylboronic acid and 12 g (1.00 mmol) of Pd[PPh₃]₄, 75 ml of toluene, 75 ml of dimethoxyethane and 75 ml (150.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 10.9 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 9 as follows (yield: 64%).

Synthesis of Intermediate 10

6.8 g (20.0 mmol) of Intermediate 9 was solubilized in 120 ml of dichloromethane, and the resulting solution was dropped into the solution of 3.2 g (20.0 mmol) of bromine in 12 ml of dichloromethane at room temperature, followed by being stirred for one hour.

After completion of the reaction, the sample was transferred to a separating funnel and washed with 2M Na₂S₂O₃ aqueous solution. The organic phase was further washed with 10% Na₂CO₃, and thereafter with water three times. The organic phase was dried with MgSO₄, followed by being filtered and concentrated.

The concentrated residue was dispersed in methanol (100 mL), and the precipitated crystal was dried to obtain 8.0 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 10 as follows (yield: 96%).

Synthesis of Compound BH-9

To 2.1 g (5.0 mmol) of Intermediate 10, 1.1 g (5.3 mmol) of dibenzofuran-2-boronic add and 0.1 g (0.1 mmol) of Pd[PPh₃]₄, 7.5 ml of toluene, 7.5 ml of dimethoxyethane and 7.5 ml (15.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating fennel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 1.6 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-9 as follows (yield: 63%).

Synthesis Example 10 [Synthesis of Compound BH-10] Synthesis of Intermediate 11

To 13.3 g (50.0 mmol) of 9-bromoanthracene-d9, 13.0 g (52.5 mmol) of 4-(1-naphthyl)phenylboronic add and 12 g (1.00 mmol) of Pd[PPh₃]₄, 75 ml of toluene, 75 ml of dimethoxyethane and 75 ml (150.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of toe reaction, having been cooled to room temperature, toe sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 15.6 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 11 as follows (yield: 80%).

Synthesis of Intermediate 12

7.8 g (20.0 mmol) of Intermediate 11 was solubilized in 120 ml of dichloromethane, and the resulting solution was dropped into the solution of 3.2 g (20.0 mmol) of bromine in 12 ml of dichloromethane at room temperature, followed by being stirred for one hour.

After completion of toe reaction, the sample was transferred to a separating funnel and washed with 2M Na₂S₂O₃ aqueous solution. The organic phase was further washed with 10% Na₂CO₃, and thereafter with water three times. The organic phase was dried with MgSO₄, followed by being filtered and concentrated.

The concentrated residue was dispersed in methanol (100 mL), and the precipitated crystal was dried to obtain 8.6 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 12 as follows (yield: 92%).

Synthesis of Compound BH-10

To 2.3 g (5.0 mmol) of Intermediate 12, 1.1 g (5.3 mmol) of dibenzofuran-2-boronic add and 0.1 g (0.1 mmol) of Pd[PPh₃]₄, 7.5 ml of toluene, 7.5 ml of dimethoxyethane and 7.5 ml (15.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 1.9 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-10 as follows (yield: 68%).

Synthesis Example 11 [Synthesis of Compound BH-11]

Except that 1.8 g (5.3 mmol) of 4-(2-dibenzofuranyl)-1-naphtalenyl boronic add was used instead of dibenzofuran-2-boronic acid, the reaction was carried out in the same way as in the synthesis example 1, thereby obtaining 1.7 g of white crystal. By conducting FD-MS analyse, the resulting compound was identified as Compound BH-11 as follows (yield: 60%)

Synthesis Example 12 [Synthesis of Compound BH-12]

Except that 1.8 g (5.3 mmol) of 6-(2-dibenzofuranyl)-2-naphtalenyl boron acid was used instead of dibenzofuran-2-boronic add, the reaction was carried out in the same way as in the synthesis example 1, thereby obtaining 1.5 g of white crystal. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-12 as follows (yield: 55%).

Synthesis Example 13 [Synthesis of Compound BH-13]

Except that 1.8 g (5.3 mmd) of 6-(2-dibenzofuranyl)-2-naphtalenyl boronic add was used instead of dibenzofuran-2-boronic acid, the reaction was carried out in the same way as in the synthesis example 2, thereby obtaining 2.0 g of white crystal. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-13 as follows (yield: 65%).

Synthesis Example 14 [Synthesis of Compound BH-14]

Except that 1.5 g (5.3 mmol) of 3-(2-dibenzofuranyl)phenyl boronic add was used instead of dibenzofuran-2-boronic add, the reaction was carried out in the same way as in the synthesis example 1, thereby obtaining 1.3 g of white crystal. By conducting FD-MS analyse, the resulting compound was identified as Compound BH-14 as follows (yield: 52%).

Synthesis Example 15 [Synthesis of Compound BH-15]

Except that 1.5 g (5.3 mmol) of 3-(2-dibenzofuranyl)phenyl boronic add was used instead of dibenzofuran-2-boronic add, the reaction was carried out in the same way as in the synthesis example 2, thereby obtaining 1.4 g of white crystal. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-15 as follows (yield: 50%).

Synthesis Example 16 [Synthesis of Compound BH-16]

Except that 1.5 g (5.3 mmol) of 4-(1-dibenzofuranyl)phenyl boronic add was used instead of dibenzofuran-2-boronic add, the reaction was carried out in the same way as in the synthesis example 1, thereby obtaining 1.6 g of white crystal. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-16 as follows (yield: 62%).

Synthesis Example 17 [Synthesis of Compound BH-17] Synthesis of Intermediate 13

To 1.33 g (5.00 mmol) of 9-bromoanthracene-d9, 0.67 g (5.25 mmol) of phenyl-d5-boronic acid and 0.12 g (0.10 mmol) of Pd[PPh₃]₄, 7.5 ml of toluene, 7.5 ml of dimethoxyethane and 7.5 ml (15.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 1.07 got white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 13 as follows (yield: 80%).

Synthesis of Intermediate 14

1.07 g (4.0 mmol) of Intermediate 13 was solubilized in 25 ml of dichloromethane, and the resulting solution was dropped into the solution of 0.64 g (4.0 mmol) of bromine in 3 ml of dichloromethane at room temperature, followed by being stirred for one hour.

After completion of the reaction, the sample was transferred to a separating funnel and washed with 2M Na₂S₂O₃ aqueous solution. The organic phase was further washed with 10% Na₂CO₃, and thereafter with water. The organic phase was dried with MgSO₄, followed by being filtered and concentrated.

The concentrated residue was dispersed in methanol (100 mL), and the precipitated crystal was dried to obtain 1.3 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Intermediate 14 as follows (yield: 95%).

Synthesis of Compound BH-17

To 0.87 g (2.5 mmol) of Intermediate 14, 0.58 g (2.65 mmol) of dibenzofuran-d7-2-boronic add and 0.06 g (0.05 mmol) of Pd[PPh₃]₄, 5 ml of toluene, 5 ml of dimethoxyethane and 5 ml (10.0 mmol) of 2M Na₂CO₃ aqueous solution were added under an atmosphere of argon, followed by being heated to reflux while stirring for 10 hours.

After completion of the reaction, having been cooled to room temperature, the sample was transferred to a separating funnel and extracted with dichloromethane. The resulting organic phase was dried with MgSO₄, followed by being filtered and concentrated. The concentrated residue was purified with silica gel column chromatography to obtain 0.77 g of white solid. By conducting FD-MS analysis, the resulting compound was identified as Compound BH-17 as follows (yield: 70%).

Example 1 (Fabrication of Organic EL Device)

A glass substrate of 25 mm by 75 mm by 1.1 mm thick with an ITO transparent electrode (anode) (manufactured by GEOMATEC Co., Ltd.) was subjected to ultrasonic cleaning in isopropyl alcohol for 5 minutes, and then subjected to UV-ozone cleaning for 30 minutes. The thickness of ITO was 130 nm.

The cleaned glass substrate with a transparent electrode was mounted in a substrate holder of a vacuum vapor deposition apparatus. First, compound HI was deposited on the surface where the transparent electrode was formed so as to cover the transparent electrode, thereby forming an HI film having a thickness of 5 nm. This HI film functioned as a hole-injecting layer.

Subsequent to the formation of the HI film, compound HT-1 was deposited to form an HT-1 film in a thickness of 80 nm on the HI film. This HT-1 film functioned as a hole-transporting layer (a first hole-transporting layer).

Subsequent to the formation of the HT-1 film, compound HT-2 was deposited to form an HT-2 film in a thickness of 10 nm on the HT-1 film. This HT-2 film functioned as an electron-blocking layer (a second hole-transporting layer).

Compound BH-1 (host material) and compound BD-1 (dopant material) were co-deposited on the HT-2 film so that the ratio of compound BD-1 was 4 mass % to form a BH-1:BD-1 film in a thickness of 25 nm. This BH-1:BD-1 film functioned as an emitting layer.

Compound ET-1 was deposited on the emitting layer to form an ET-1 film in a thickness of 10 nm. This ET-1 film functioned as a hole-barrier layer.

Compound ET-2 was deposited on the ET-1 layer to form an ET-2 layer in a thickness of 15 nm. This ET-2 layer functioned as an electron-transporting layer. LiF was deposited on the ET-2 layer to form a LiF film in a thickness of 1 nm. A1 metal was deposited on the LiF film to form a metal cathode in a thickness of 80 nm. An organic EL device was thus fabricated.

The layer construction of the fabricated organic EL device was as follows. ITO (130)/HI (5)/HT-1 (80)/HT-2 (10)/BH-1:BD-1 (25:4 mass %)/ET-1 (10)/ET-2 (15)/LiF (1)/Al (80)

The numbers in the parenthesis denote the thickness of each layer (unit: nm).

The compounds used in Example 1 as well as the subsequent examples and comparative examples are shown below.

(Evaluation of Organic EL Device)

A voltage was applied to the obtained organic EL device so that the current density was 50 mA/cm², and the time until the luminance reached 95% with respect to the initial luminance (LT95) was measured. The results are shown in Table 1.

Further, a voltage was applied to the obtained organic EL device so that the current density was 10 mA/cm², and spectral radiance spectrum was measured using a spectroradimeter “CS-1000” (manufactured by Konica Minolta, Inc.) to determine CIE1931 chromaticity coordinate (CIEx, CIEy). The results are shown in Table 1.

Comparative Example 1

Except that the compound shown in the blowing table was used as the host material of the emitting layer, the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 1.

TABLE 1 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 1 BH-1 BD-1 155 0.139 0.090 Comparative BH-1-a BD-1 94 0.139 0.090 Example 1

Example 2, Comparative Example 2

Except that the compounds shown in Table 2 were used as the materials of the emitting layer, the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 2.

TABLE 2 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 2 BH-1 BD-2 43 0.137 0.068 Comparative BH-1-a BD-2 28 0.137 0.067 Example 2

Example 3, Comparative Example 3

Except that the compounds shown in Table 3 were used as the materials of the emitting layer, the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 3.

TABLE 3 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 3 BH-2 BD-1 80 0.139 0.090 Comparative BH-2-a BD-1 49 0.139 0.090 Example 3

Example 4, Comparative Example 4

Except that the compounds shown in Table 4 were used as the materials of the emitting layer, the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 4.

TABLE 4 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 4 BH-2 BD-2 25 0.137 0.067 Comparative BH-2-a BD-2 15 0.137 0.067 Example 4

Example 5, Comparative Example 5

Except that the compounds shown in Table 5 were used as the materials of the emitting layer, the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 5.

TABLE 5 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 5 BH-3 BD-1 70 0.139 0.090 Comparative BH-3-a BD-1 40 0.139 0.090 Example 5

Example 6, Comparative Example 6

Except that the compounds shown in Table 6 were used as the materials of the emitting layer, the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 6.

TABLE 6 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 6 BH-3 BD-2 20 0.137 0.067 Comparative BH-3-a BD-2 12 0.137 0.067 Example 6

Example 7, Comparative Example 7

Except that the compounds shown in Table 7 were used as the materials of the emitting layer, the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shewn in Table 7.

TABLE 7 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 7 BH-4 BD-1 65 0.139 0.090 Comparative BH-4-a BD-1 38 0.139 0.090 Example 7

Example 8, Comparative Example 8

Except that the compounds shown in Table 8 were used as the materials of the emitting layer, the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 8.

TABLE 8 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 8 BH-4 BD-2 20 0.137 0.065 Comparative BH-4-a BD-2 13 0.137 0.065 Example 8

Example 11, Comparative Example 11

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 9.

TABLE 9 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 11 BH-1 BD-3 130 0.140 0.080 Comparative BH-1-a BD-3 83 0.140 0.080 Example 11

Example 12, Comparative Example 12

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 10.

TABLE 10 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 12 BH-2 BD-3 71 0.140 0.081 Comparative BH-2-a BD-3 45 0.140 0.080 Example 12

Example 13, Comparative Example 13

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 11.

TABLE 11 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 13 BH-3 BD-3 56 0.140 0.080 Comparative BH-3-a BD-3 36 0.140 0.080 Example 13

Example 14, Comparative Example 14

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 12.

TABLE 12 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 14 BH-4 BD-3 57 0.140 0.080 Comparative BH-4-a BD-3 30 0.140 0.080 Example 14

Example 15, Comparative Example 15

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in foe same manner as in Example 1. The results are shown in Table 13.

TABLE 13 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 15 BH-5 BD-3 146 0.140 0.080 Comparative BH-5-a BD-3 82 0.140 0.080 Example 15

Example 16, Comparative Example 16

Except that the compounds shown in the following table were used as the materials of foe emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 14.

TABLE 14 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 16 BH-6 BD-3 126 0.140 0.080 Comparative BH-6-a BD-3 78 0.140 0.080 Example 16

Example 17, Comparative Example 17

Except that the compounds shown in the following table were used as the materials of foe emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 15.

TABLE 15 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 17 BH-7 BD-3 127 0.140 0.080 Comparative BH-7-a BD-3 80 0.140 0.080 Example 17

Example 21, Comparative Example 21

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 16.

TABLE 16 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 21 BH-1 BD-4 155 0.135 0.098 Comparative BH-1-a BD-4 96 0.135 0.098 Example 21

Example 22, Comparative Example 22

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 17.

TABLE 17 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 22 BH-2 BD-4 77 0.135 0.098 Comparative BH-2-a BD-4 50 0.135 0.099 Example 22

Example 23, Comparative Example 23

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 18.

TABLE 18 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 23 BH-3 BD-4 73 0.135 0.098 Comparative BH-3-a BD-4 43 0.135 0.098 Example 23

Example 24, Comparative Example 24

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 19.

TABLE 19 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 24 BH-4 BD-4 60 0.135 0.098 Comparative BH-4-a BD-4 41 0.135 0.098 Example 24

Example 25, Comparative Example 25

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 20.

TABLE 20 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 25 BH-5 BD-4 167 0.135 0.098 Comparative BH-5-a BD-4 105 0.135 0.098 Example 25

Example 26, Comparative Example 26

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 21.

TABLE 21 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 26 BH-6 BD-4 147 0.135 0.098 Comparative BH-6-a BD-4 92 0.135 0.098 Example 26

Example 27, Comparative Example 27

Except that the compounds shown In the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 22.

TABLE 22 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 27 BH-7 BD-4 150 0.135 0.098 Comparative BH-7-a BD-4 96 0.135 0.098 Example 27

Example 31, Comparative Example 31

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 23.

TABLE 23 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 31 BH-1 BD-5 163 0.135 0.086 Comparative BH-1-a BD-5 98 0.135 0.086 Example 31

Example 32, Comparative Example 32

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 24.

TABLE 24 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 32 BH-2 BD-5 78 0.135 0.086 Comparative BH-2-a BD-5 51 0.135 0.086 Example 32

Example 33, Comparative Example 33

Except that the compounds shown in the following (able were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 25.

TABLE 25 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 33 BH-3 BD-5 73 0.135 0.086 Comparative BH-3-a BD-5 39 0.135 0.086 Example 33

Example 34, Comparative Example 34

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 26.

TABLE 26 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 34 BH-4 BD-5 62 0.135 0.085 Comparative BH-4-a BD-5 43 0.135 0.086 Example 34

Example 35, Comparative Example 35

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 27.

TABLE 27 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 35 BH-5 BD-5 170 0.135 0.086 Comparative BH-5-a BD-5 105 0.135 0.086 Example 35

Example 36, Comparative Example 36

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 28.

TABLE 28 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 36 BH-6 BD-5 152 0.135 0.086 Comparative BH-6-a BD-5 89 0.135 0.086 Example 36

Example 37, Comparative Example 37

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 29.

TABLE 29 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 37 BH-7 BD-5 161 0.135 0.086 Comparative BH-7-a BD-5 102 0.135 0.086 Example 37

Example 41, Comparative Example 41

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 30.

TABLE 30 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 41 BH-1 BD-6 195 0.135 0.080 Comparative BH-1-a BD-6 123 0.135 0.080 Example 41

Example 42, Comparative Example 42

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 31.

TABLE 31 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 42 BH-2 BD-6 106 0.135 0.080 Comparative BH-2-a BD-6 66 0.135 0.080 Example 42

Example 43, Comparative Example 43

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 32.

TABLE 32 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 43 BH-3 BD-6 90 0.135 0.080 Comparative BH-3-a BD-6 53 0.135 0.080 Example 43

Example 44, Comparative Example 44

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 33.

TABLE 33 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 44 BH-4 BD-6 84 0.135 0.080 Comparative BH-4-a BD-6 52 0.135 0.080 Example 44

Example 45, Comparative Example 45

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 34.

TABLE 34 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 45 BH-5 BD-6 211 0.135 0.080 Comparative BH-5-a BD-6 133 0.135 0.081 Example 45

Example 46, Comparative Example 46

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 35.

TABLE 35 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 46 BH-6 BD-6 179 0.135 0.080 Comparative BH-6-a BD-6 112 0.135 0.080 Example 46

Example 47, Comparative Example 47

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 36.

TABLE 36 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 47 BH-7 BD-6 202 0.135 0.080 Comparative BH-7-a BD-6 125 0.135 0.080 Example 47

Example 51, Comparative Example 51

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 37.

TABLE 37 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 51 BH-1 BD-7 253 0.136 0.090 Comparative BH-1-a BD-7 146 0.136 0.090 Example 51

Example 52, Comparative Example 52

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 38.

TABLE 38 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 52 BH-2 BD-7 125 0.136 0.090 Comparative BH-2-a BD-7 73 0.136 0.090 Example 52

Example 53, Comparative Example 53

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown In Table 39.

TABLE 39 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 53 BH-3 BD-7 102 0.136 0.090 Comparative BH-3-a BD-7 64 0.136 0.090 Example 53

Example 54, Comparative Example 54

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 40.

TABLE 40 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 54 BH-4 BD-7 99 0.136 0.090 Comparative BH-4-a BD-7 64 0.136 0.090 Example 54

Example 55, Comparative Example 55

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 41.

TABLE 41 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 55 BH-5 BD-7 257 0.136 0.090 Comparative BH-5-a BD-7 161 0.136 0.091 Example 55

Example 56, Comparative Example 56

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated In the same manner as in Example 1. The results are shown in Table 42.

TABLE 42 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 56 BH-6 BD-7 215 0.136 0.090 Comparative BH-6-a BD-7 137 0.136 0.090 Example 56

Example 57, Comparative Example 57

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 43.

TABLE 43 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 57 BH-7 BD-7 241 0.136 0.090 Comparative BH-7-a BD-7 141 0.136 0.090 Example 57

Example 61, Comparative Example 61

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 44.

TABLE 44 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 61 BH-1 BD-8 104 0.144 0.061 Comparative BH-1-a BD-8 65 0.144 0.061 Example 61

Example 62, Comparative Example 62

Except that the compounds shown In the following fable were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 45.

TABLE 45 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 62 BH-2 BD-8 53 0.144 0.061 Comparative BH-2-a BD-8 37 0.144 0.061 Example 62

Example 63, Comparative Example 63

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 46.

TABLE 46 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 63 BH-3 BD-8 51 0.144 0.060 Comparative BH-3-a BD-8 32 0.144 0.061 Example 63

Example 64, Comparative Example 64

Except that the compounds shown in the following fable were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 47.

TABLE 47 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 64 BH-4 BD-8 47 0.144 0.061 Comparative BH-4-a BD-8 29 0.144 0.061 Example 64

Example 65, Comparative Example 65

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 48.

TABLE 48 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 65 BH-5 BD-8 117 0.144 0.061 Comparative BH-5-a BD-8 75 0.144 0.061 Example 65

Example 66, Comparative Example 66

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 49.

TABLE 49 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 66 BH-6 BD-8 105 0.144 0.061 Comparative BH-6-a BD-8 65 0.144 0.061 Example 66

Example 67, Comparative Example 67

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 50.

TABLE 50 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 67 BH-7 BD-8 110 0.144 0.061 Comparative BH-7-a BD-8 66 0.144 0.061 Example 67

Example 68, Comparative Example 68

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 51.

TABLE 51 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 68 BH-1 BD-9 111 0.141 0.056 Comparative BH-1-a BD-9 88 0.141 0.056 Example 68

Example 69, Comparative Example 69

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 52.

TABLE 52 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 69 BH-2 BD-9 65 0.141 0.056 Comparative BH-2-a BD-9 46 0.141 0.056 Example 69

Example 70, Comparative Example 70

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 53.

TABLE 53 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 70 BH-3 BD-9 60 0.141 0.056 Comparative BH-3-a BD-9 42 0.141 0.056 Example 70

Example 71, Comparative Example 71

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 54.

TABLE 54 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 71 BH-5 BD-9 137 0.141 0.057 Comparative BH-5-a BD-9 94 0.141 0.057 Example 71

Example 72, Comparative Example 72

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 55.

TABLE 55 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 72 BH-6 BD-9 118 0.141 0.056 Comparative BH-6-a BD-9 84 0.141 0.056 Example 72

Example 73, Comparative Example 73

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 56.

TABLE 56 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 73 BH-7 BD-9 136 0.141 0.056 Comparative BH-7-a BD-9 88 0.141 0.056 Example 73

Example 74, Comparative Example 74

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 57.

TABLE 57 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 74 BH-8 BD-9 89 0.141 0.056 Comparative BH-8-a BD-9 63 0.141 0.056 Example 74

Example 75, Comparative Example 75

Except that the compounds shown in the following fable were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 58.

TABLE 58 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 75 BH-9 BD-9 100 0.141 0.056 Comparative BH-9-a BD-9 66 0.141 0.056 Example 75

Example 76, Comparative Example 76

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 59.

TABLE 59 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 76 BH-10 BD-9 90 0.141 0.056 Comparative BH-10-a BD-9 61 0.141 0.056 Example 76

Example 77, Comparative Example 77

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 60.

TABLE 60 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 77 BH-11 BD-9 77 0.141 0.056 Comparative BH-11-a BD-9 55 0.141 0.056 Example 77

Example 78, Comparative Example 78

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 61.

TABLE 61 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 78 BH-12 BD-9 73 0.141 0.057 Comparative BH-12-a BD-9 47 0.141 0.057 Example 78

Example 79, Comparative Example 79

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 62.

TABLE 62 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 79 BH-13 BD-9 66 0.141 0.056 Comparative BH-13-a BD-9 44 0.141 0.056 Example 79

Example 80, Comparative Example 80

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 63.

TABLE 63 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 80 BH-14 BD-9 115 0.141 0.056 Comparative BH-14-a BD-9 83 0.141 0.056 Example 80

Example 81, Comparative Example 81

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 64.

TABLE 64 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 81 BH-15 BD-9 80 0.141 0.056 Comparative BH-15-a BD-9 55 0.141 0.056 Example 81

Example 82, Comparative Example 82

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 65.

TABLE 65 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 82 BH-16 BD-9 72 0.141 0.056 Comparative BH-16-a BD-9 55 0.141 0.056 Example 82

Example 83

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 66.

TABLE 66 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 83 BH-17 BD-9 110 0.141 0.056

Example 84, Comparative Example 84

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 67.

TABLE 67 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 84 BH-1 BD-10 203 0.133 0.078 Comparative BH-1-a BD-10 143 0.133 0.078 Example 84

Example 85, Comparative Example 85

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 68.

TABLE 68 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 85 BH-2 BD-10 111 0.133 0.078 Comparative BH-2-a BD-10 77 0.133 0.078 Example 85

Example 86, Comparative Example 86

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 69.

TABLE 69 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 86 BH-3 BD-10 93 0.133 0.078 Comparative BH-3-a BD-10 64 0.133 0.078 Example 86

Example 87, Comparative Example 87

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 70.

TABLE 70 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 87 BH-5 BD-10 217 0.133 0.079 Comparative BH-5-a BD-10 154 0.133 0.079 Example 87

Example 88, Comparative Example 88

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 71.

TABLE 71 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 88 BH-6 BD-10 208 0.133 0.078 Comparative BH-6-a BD-10 138 0.133 0.078 Example 88

Example 89, Comparative Example 89

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 72.

TABLE 72 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 89 BH-7 BD-10 218 0.133 0.078 Comparative BH-7-a BD-10 143 0.133 0.078 Examole 89

Example 90, Comparative Example 90

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 73.

TABLE 73 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 90 BH-8 BD-10 155 0.133 0.078 Comparative BH-8-a BD-10 110 0.133 0.078 Example 90

Example 91, Comparative Example 91

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 74.

TABLE 74 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 91 BH-9 BD-10 151 0.133 0.078 Comparative BH-9-a BD-10 110 0.133 0.078 Example 91

Example 92, Comparative Example 92

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in foe same manner as in Example 1. The results are shown in Table 75.

TABLE 75 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 92 BH-10 BD-10 161 0.133 0.078 Comparative BH-10-a BD-10 105 0.133 0.078 Example 92

Example 93, Comparative Example 93

Except that the compounds shown in the following table were used as the materials of foe emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 76.

TABLE 76 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 93 BH-11 BD-10 137 0.133 0.078 Comparative BH-11-a BD-10 92 0.133 0.078 Example 93

Example 94, Comparative Example 94

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 77.

TABLE 77 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 94 BH-12 BD-10 117 0.133 0.079 Comparative BH-12-a BD-10 77 0.133 0.079 Example 94

Example 95, Comparative Example 95

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 78.

TABLE 78 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 95 BH-13 BD-10 113 0.133 0.078 Comparative BH-13-a BD-10 75 0.133 0.078 Example 95

Example 96, Comparative Example 96

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 79.

TABLE 79 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 96 BH-14 BD-10 191 0.133 0.078 Comparative BH-14-a BD-10 138 0.133 0.078 Example 96

Example 97, Comparative Example 97

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 80.

TABLE 80 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 97 BH-15 BD-10 138 0.133 0.078 Comparative BH-15-a BD-10 94 0.133 0.078 Example 97

Example 98, Comparative Example 98

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 81.

TABLE 81 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 98 BH-16 BD-10 141 0.133 0.078 Comparative BH-16-a BD-10 90 0.133 0.078 Example 98

Example 99

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 82.

TABLE 82 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 99 BH-17 BD-11 209 0.133 0.078

Example 100, Comparative Example 100

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 83.

TABLE 83 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 100 BH-1 BD-11 191 0.133 0.076 Comparative BH-1-a BD-11 138 0.133 0.076 Example 100

Example 101, Comparative Example 101

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 84.

TABLE 84 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 101 BH-2 BD-11 97 0.133 0.076 Comparative BH-2-a BD-11 72 0.133 0.076 Example 101

Example 102, Comparative Example 102

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 85.

TABLE 85 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 102 BH-3 BD-11 91 0.133 0.076 Comparative BH-3-a BD-11 61 0.133 0.076 Example 102

Example 103, Comparative Example 103

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 86.

TABLE 86 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 103 BH-5 BD-11 207 0.133 0.077 Comparative BH-5-a BD-11 147 0.133 0.077 Example 103

Example 104, Comparative Example 104

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 87.

TABLE 87 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 104 BH-6 BD-11 181 0.133 0.076 Comparative BH-6-a BD-11 132 0.133 0.076 Example 104

Example 105, Comparative Example 105

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 88.

TABLE 88 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 105 BH-7 BD-11 199 0.133 0.076 Comparative BH-7-a BD-11 138 0.133 0.076 Example 105

Example 106, Comparative Example 106

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 89.

TABLE 89 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 106 BH-8 BD-11 153 0.133 0.076 Comparative BH-8-a BD-11 105 0.133 0.076 Example 106

Example 107, Comparative Example 107

Except that the compounds shown in the following fable were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 90.

TABLE 90 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 107 BH-9 BD-11 145 0.133 0.076 Comparative BH-9-a BD-11 102 0.133 0.076 Example 107

Example 108, Comparative Example 108

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 91.

TABLE 91 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 108 BH-10 BD-11 124 0.133 0.076 Comparative BH-10-a BD-11 97 0.133 0.076 Example 108

Example 109, Comparative Example 109

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 92.

TABLE 92 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 109 BH-11 BD-11 108 0.133 0.076 Comparative BH-11-a BD-11 83 0.133 0.076 Example 109

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 93.

TABLE 93 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 110 BH-12 BD-11 101 0.133 0.077 Comparative BH-12-a BD-11 74 0.133 0.077 Example 110

Example 111, Comparative Example 111

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 94.

TABLE 94 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 111 BH-13 BD-11 102 0.133 0.076 Comparative BH-13-a BD-11 66 0.133 0.076 Example 111

Example 112, Comparative Example 112

Except that the compounds shown in the following table were used as the materials of foe emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 95.

TABLE 95 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 112 BH-14 BD-11 186 0.133 0.076 Comparative BH-14-a BD-11 130 0.133 0.076 Example 112

Example 113, Comparative Example 113

Except that the compounds shown in the following table were used as the materials of foe emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 96.

TABLE 96 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 113 BH-15 BD-11 128 0.133 0.076 Comparative BH-15-a BD-11 88 0.133 0.076 Example 113

Example 114, Comparative Example 114

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 97.

TABLE 97 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 114 BH-16 BD-11 128 0.133 0.076 Comparative BH-16-a BD-11 87 0.133 0.076 Example 114

Example 115

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 98.

TABLE 98 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 115 BH-17 BD-11 190 0.133 0.076

Example 116, Comparative Example 116

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 99.

TABLE 99 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 116 BH-1 BD-12 123 0.141 0.058 Comparative BH-1-a BD-12 94 0.141 0.058 Example 116

Example 117, Comparative Example 117

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 100.

TABLE 100 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 117 BH-2 BD-12 70 0.141 0.058 Comparative BH-2-a BD-12 52 0.141 0.058 Example 117

Example 118, Comparative Example 118

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 101.

TABLE 101 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 118 BH-3 BD-12 66 0.141 0.058 Comparative BH-3-a BD-12 44 0.141 0.058 Example 118

Example 119, Comparative Example 119

Except that the compounds shown in following fable were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 102.

TABLE 102 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 119 BH-5 BD-12 149 0.141 0.059 Comparative BH-5-a BD-12 101 0.141 0.059 Example 119

Example 120, Comparative Example 120

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 103.

TABLE 103 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 120 BH-6 BD-12 123 0.141 0.058 Comparative BH-6-a BD-12 92 0.141 0.058 Example 120

Example 121, Comparative Example 121

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 104.

TABLE 104 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 121 BH-7 BD-12 145 0.141 0.058 Comparative BH-7-a BD-12 96 0.141 0.058 Example 121

Example 122, Comparative Example 122

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 105.

TABLE 105 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 122 BH-8 BD-12 115 0.141 0.058 Comparative BH-8-a BD-12 79 0.141 0.058 Example 122

Example 123, Comparative Example 123

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 106.

TABLE 106 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 123 BH-9 BD-12 106 0.141 0.058 Comparative BH-9-a BD-12 72 0.141 0.058 Example 123

Example 124, Comparative Example 124

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 107.

TABLE 107 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 124 BH-10 BD-12 98 0.141 0.058 Comparative BH-10-a BD-12 65 0.141 0.058 Example 124

Example 125, Comparative Example 125

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 108.

TABLE 108 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 125 BH-11 BD-12 82 0.141 0.058 Comparative BH-11-a BD-12 57 0.141 0.058 Example 125

Example 126, Comparative Example 126

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 109.

TABLE 109 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 126 BH-12 BD-12 79 0.141 0.059 Comparative BH-12-a BD-12 52 0.141 0.059 Example 126

Example 127, Comparative Example 127

Except that the compounds shown in the following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 110.

TABLE 110 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 127 BH-13 BD-12 79 0.141 0.058 Comparative BH-13-a BD-12 55 0.141 0.058 Example 127

Example 128, Comparative Example 128

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 111.

TABLE 111 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 128 BH-14 BD-12 123 0.141 0.058 Comparative BH-14-a BD-12 88 0.141 0.058 Example 128

Example 129, Comparative Example 129

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 112.

TABLE 112 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 129 BH-15 BD-12 93 0.141 0.058 Comparative BH-15-a BD-12 63 0.141 0.058 Example 129

Example 130, Comparative Example 130

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 113.

TABLE 113 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 130 BH-16 BD-12 81 0.141 0.058 Comparative BH-16-a BD-12 61 0.141 0.058 Example 130

Example 131

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in Table 114.

TABLE 114 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 131 BH-17 BD-12 120 0.141 0.058

Example 132 and Comparative Example 132

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 115 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 132 BH-8 BD-3 98 0.140 0.080 Comparative BH-8-a BD-3 64 0.140 0.080 Example 132

Example 133 and Comparative Example 133

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 116 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 133 BH-9 BD-3 100 0.140 0.080 Comparative BH-9-a BD-3 64 0.140 0.080 Example 133

Example 134 and Comparative Example 134

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 117 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 134 BH-10 BD-3 94 0.140 0.080 Comparative BH-10-a BD-3 58 0.140 0.080 Example 134

Example 135 and Comparative Example 135

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 118 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 135 BH-11 BD-3 83 0.140 0.081 Comparative BH-11-a BD-3 50 0.140 0.080 Example 135

Example 136 and Comparative Example 136

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 119 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 136 BH-12 BD-3 73 0.140 0.080 Comparative BH-12-a BD-3 45 0.140 0.080 Example 136

Example 137 and Comparative Example 137

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 120 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 137 BH-13 BD-3 65 0.140 0.080 Comparative BH-13-a BD-3 40 0.140 0.080 Example 137

Example 138 and Comparative Example 138

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 121 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 138 BH-14 BD-3 127 0.140 0.080 Comparative BH-14-a BD-3 75 0.140 0.080 Example 138

Example 139 and Comparative Example 139

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 122 Emitting layer Hosting Dopant Chromaticity material material LT95(h) CIEx CIEy Example 139 BH-15 BD-3 88 0.140 0.080 Comparative BH-15-a BD-3 54 0.140 0.080 Example 139

Example 140 and Comparative Example 140

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 123 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 140 BH-16 BD-3 84 0.140 0.080 Comparative BH-16-a BD-3 52 0.140 0.080 Example 140

Example 141

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 124 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 141 BH-17 BD-3 131 0.140 0.080

Example 142 and Comparative Example 142

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 125 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 142 BH-8 BD-4 118 0.135 0.098 Comparative BH-8-a BD-4 75 0.135 0.098 Example 142

Example 143 and Comparative Example 143

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 126 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 143 BH-9 BD-4 112 0.135 0.098 Comparative BH-9-a BD-4 72 0.135 0.098 Example 143

Example 144 and Comparative Example 144

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 127 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 144 BH-10 BD-4 105 0.135 0.098 Comparative BH-10-a BD-4 66 0.135 0.098 Example 144

Example 145 and Comparative Example 145

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 128 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 145 BH-11 BD-4 90 0.135 0.098 Comparative BH-11-a BD-4 60 0.135 0.098 Example 145

Example 146 and Comparative Example 146

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 129 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 146 BH-12 BD-4 80 0.135 0.098 Comparative BH-12-a BD-4 53 0.135 0.098 Example 146

Example 147 and Comparative Example 147

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 130 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 147 BH-13 BD-4 70 0.135 0.098 Comparative BH-13-a BD-4 46 0.135 0.098 Example 147

Example 148 and Comparative Example 148

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 131 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 148 BH-14 BD-4 150 0.135 0.098 Comparative BH-14-a BD-4 92 0.135 0.098 Example 148

Example 149 and Comparative Example 149

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 132 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 149 BH-15 BD-4 102 0.135 0.098 Comparative BH-15-a BD-4 64 0.135 0.098 Example 149

Example 150 and Comparative Example 150

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 133 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 150 BH-16 BD-4 96 0.135 0.098 Comparative BH-16-a BD-4 60 0.135 0.099 Example 150

Example 151

Except that the compounds shown in following table were used as the materials erf the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 134 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 151 BH-17 BD-4 157 0.135 0.098

Example 152 and Comparative Example 152

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 135 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 152 BH-8 BD-5 126 0.135 0.086 Comparative BH-8-a BD-5 80 0.135 0.086 Example 152

Example 153 and Comparative Example 153

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 136 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 153 BH-9 BD-5 126 0.135 0.086 Comparative BH-9-a BD-5 76 0.135 0.086 Example 153

Example 154 and Comparative Example 154

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 137 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 154 BH-10 BD-5 110 0.135 0.085 Comparative BH-10-a BD-5 70 0.135 0.086 Example 154

Example 155 and Comparative Example 155

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 138 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 155 BH-11 BD-5 103 0.135 0.086 Comparative BH-11-a BD-5 60 0.135 0.086 Example 155

Example 156 and Comparative Example 156

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 139 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 156 BH-12 BD-5 90 0.135 0.086 Comparative BH-12-a BD-5 56 0.135 0.086 Example 156

Example 157 and Comparative Example 157

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 140 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 157 BH-13 BD-5 80 0.135 0.086 Comparative BH-13-a BD-5 50 0.135 0.086 Example 157

Example 158 and Comparative Example 158

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 141 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 158 BH-14 BD-5 157 0.135 0.086 Comparative BH-14-a BD-5 92 0.135 0.085 Example 158

Example 159 and Comparative Example 159

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 142 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 159 BH-15 BD-5 110 0.135 0.086 Comparative BH-15-a BD-5 65 0.135 0.086 Example 159

Example 160 and Comparative Example 160

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 143 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 160 BH-16 BD-5 100 0.135 0.086 Comparative BH-16-a BD-5 60 0.135 0.086 Example 160

Example 161

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 144 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 161 BH-17 BD-5 165 0.135 0.086

Example 162 and Comparative Example 162

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 145 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 162 BH-8 BD-6 150 0.135 0.080 Comparative BH-8-a BD-6 90 0.135 0.080 Example 162

Example 163 and Comparative Example 163

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The resists are shown in the following Table.

TABLE 146 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 163 BH-9 BD-6 155 0.135 0.080 Comparative BH-9-a BD-6 90 0.135 0.080 Example 163

Example 164 and Comparative Example 164

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 147 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 164 BH-10 BD-6 143 0.135 0.080 Comparative BH-10-a BD-6 88 0.135 0.080 Example 164

Example 165 and Comparative Example 165

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated fa the same manner as in Example 1. The results are shown in the following Table.

TABLE 148 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 165 BH-11 BD-6 124 0.135 0.080 Comparative BH-11-a BD-6 75 0.135 0.080 Example 165

Example 166 and Comparative Example 166

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 149 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 166 BH-12 BD-6 106 0.135 0.080 Comparative BH-12-a BD-6 68 0.135 0.080 Example 166

Example 167 and Comparative Example 167

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 150 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 167 BH-13 BD-6 90 0.135 0.081 Comparative BH-13-a BD-6 62 0.135 0.080 Example 167

Example 168 and Comparative Example 168

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 151 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 168 BH-14 BD-6 195 0.135 0.080 Comparative BH-14-a BD-6 117 0.135 0.080 Example 168

Example 169 and Comparative Example 169

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated fa the same manner as in Example 1. The results are shown in the following Table.

TABLE 152 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 169 BH-15 BD-6 138 0.135 0.080 Comparative BH-15-a BD-6 80 0.135 0.080 Example 169

Example 170 and Comparative Example 170

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 153 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 170 BH-16 BD-6 130 0.135 0.080 Comparative BH-16-a BD-6 77 0.135 0.080 Example 170

Example 171

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 154 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 171 BH-17 BD-6 200 0.135 0.080

Example 172 and Comparative Example 172

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 155 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 172 BH-8 BD-7 190 0.136 0.090 Comparative BH-8-a BD-7 114 0.136 0.090 Example 172

Example 173 and Comparative Example 173

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 156 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 173 BH-9 BD-7 179 0.136 0.090 Comparative BH-9-a BD-7 110 0.136 0.090 Example 173

Example 174 and Comparative Example 174

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 157 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 174 BH-10 BD-7 164 0.136 0.090 Comparative BH-10-a BD-7 98 0.136 0.090 Example 174

Example 175 and Comparative Example 175

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 158 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 175 BH-11 BD-7 147 0.136 0.090 Comparative BH-11-a BD-7 88 0.136 0.090 Example 175

Example 176 and Comparative Example 176

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 159 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 176 BH-12 BD-7 122 0.136 0.090 Comparative BH-12-a BD-7 80 0.136 0.090 Example 176

Example 177 and Comparative Example 177

Except that the compounds shown in following fable were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 160 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 177 BH-13 BD-7 118 0.136 0.090 Comparative BH-13-a BD-7 72 0.136 0.090 Example 177

Example 178 and Comparative Example 178

Except that the compounds shown in following fable were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 161 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 178 BH-14 BD-7 242 0.136 0.090 Comparative BH-14-a BD-7 140 0.136 0.090 Example 178

Example 179 and Comparative Example 179

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 162 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 179 BH-15 BD-7 155 0.136 0.090 Comparative BH-15-a BD-7 92 0.136 0.090 Example 179

Example 180 and Comparative Example 180

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 163 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 180 BH-16 BD-7 146 0.144 0.061 Comparative BH-16-a BD-7 90 0.144 0.061 Example 180

Example 181

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 164 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 181 BH-17 BD-7 245 0.136 0.090

Example 182 and Comparative Example 182

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 165 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 182 BH-8 BD-8 82 0.144 0.061 Comparative BH-8-a BD-8 50 0.144 0.061 Example 182

Example 183 and Comparative Example 183

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 166 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 183 BH-9 BD-8 82 0.144 0.061 Comparative BH-9-a BD-8 50 0.144 0.061 Example 183

Example 184 and Comparative Example 184

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 167 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 184 BH-10 BD-8 74 0.144 0.060 Comparative BH-10-a BD-8 48 0.144 0.060 Example 184

Example 185 and Comparative Example 185

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 168 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 185 BH-11 BD-8 63 0.144 0.061 Comparative BH-11-a BD-8 42 0.144 0.061 Example 185

Example 186 and Comparative Example 186

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 169 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 186 BH-12 BD-8 61 0.144 0.061 Comparative BH-12-a BD-8 37 0.144 0.061 Example 186

Example 187 and Comparative Example 187

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 170 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 187 BH-13 BD-8 55 0.144 0.061 Comparative BH-13-a BD-8 33 0.144 0.061 Example 187

Example 188 and Comparative Example 188

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 171 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 188 BH-14 BD-8 105 0.144 0.061 Comparative BH-14-a BD-8 65 0.144 0.061 Example 188

Example 189 and Comparative Example 189

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 172 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 189 BH-15 BD-8 75 0.144 0.061 Comparative BH-15-a BD-8 50 0.144 0.061 Example 189

Example 190 and Comparative Example 190

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 173 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 190 BH-16 BD-8 70 0.144 0.061 Comparative BH-16-a BD-8 43 0.144 0.061 Example 190

Example 191

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 174 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 191 BH-17 BD-8 107 0.144 0.061

Example 192 and Comparative Example 192

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 175 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 192 BH-1 BD-13 129 0.138 0.117 Comparative BH-1-a BD-13 87 0.138 0.117 Example 192

Example 193 and Comparative Example 193

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 176 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 193 BH-2 BD-13 67 0.138 0.117 Comparative BH-2-a BD-13 44 0.138 0.117 Example 193

Example 194 and Comparative Example 194

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 177 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 194 BH-3 BD-13 57 0.138 0.117 Comparative BH-3-a BD-13 40 0.138 0.117 Example 194

Example 195 and Comparative Example 195

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 178 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 195 BH-4 BD-13 54 0.138 0.117 Comparative BH-4-a BD-13 40 0.138 0.117 Example 195

Example 196 and Comparative Example 196

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 179 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 196 BH-5 BD-13 140 0.138 0.117 Comparative BH-5-a BD-13 92 0.138 0.117 Example 196

Example 197 and Comparative Example 197

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The resets are shown in the following Table.

TABLE 180 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 197 BH-6 BD-13 123 0.138 0.118 Comparative BH-6-a BD-13 80 0.138 0.118 Example 197

Example 198 and Comparative Example 198

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 181 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 198 BH-7 BD-13 129 0.138 0.117 Comparative BH-7-a BD-13 90 0.138 0.117 Example 198

Example 199 and Comparative Example 199

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 182 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 199 BH-8 BD-13 95 0.138 0.117 Comparative BH-8-a BD-13 67 0.138 0.117 Example 199

Example 200 and Comparative Example 200

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 183 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 200 BH-9 BD-13 94 0.138 0.117 Comparative BH-9-a BD-13 63 0.138 0.117 Example 200

Example 201 and Comparative Example 201

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 184 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 201 BH-10 BD-13 88 0.138 0.117 Comparative BH-10-a BD-13 63 0.138 0.117 Example 201

Example 202 and Comparative Example 202

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 185 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 202 BH-11 BD-13 72 0.138 0.117 Comparative BH-11-a BD-13 52 0.138 0.117 Example 202

Example 203 and Comparative Example 203

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 186 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 203 BH-12 BD-13 70 0.138 0.118 Comparative BH-12-a BD-13 48 0.138 0.118 Example 203

Example 204 and Comparative Example 204

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 187 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 204 BH-13 BD-13 63 0.138 0.117 Comparative BH-13-a BD-13 48 0.138 0.117 Example 204

Example 205 and Comparative Example 205

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 188 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 205 BH-14 BD-13 128 0.138 0.117 Comparative BH-14-a BD-13 84 0.138 0.117 Example 205

Example 206 and Comparative Example 206

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 189 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 206 BH-15 BD-13 81 0.138 0.117 Comparative BH-15-a BD-13 59 0.138 0.117 Example 206

Example 207 and Comparative Example 207

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 190 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 207 BH-16 BD-13 82 0.138 0.117 Comparative BH-16-a BD-13 56 0.138 0.117 Example 207

Example 208

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 191 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 208 BH-17 BD-13 117 0.138 0.117

Example 209 and Comparative Example 209

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 192 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 209 BH-1 BD-14 108 0.139 0.121 Comparative BH-1-a BD-14 72 0.139 0.121 Example 209

Example 210 and Comparative Example 210

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 193 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 210 BH-2 BD-14 50 0.139 0.121 Comparative BH-2-a BD-14 35 0.139 0.121 Example 210

Example 211 and Comparative Example 211

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated fa the same manner as in Example 1. The results are shown in the following Table.

TABLE 194 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 211 BH-3 BD-14 49 0.139 0.121 Comparative BH-3-a BD-14 35 0.139 0.121 Example 211

Example 212 and Comparative Example 212

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 195 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 212 BH-4 BD-14 47 0.139 0.121 Comparative BH-4-a BD-14 32 0.139 0.121 Example 212

Example 213 and Comparative Example 213

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The resists are shown in the following Table.

TABLE 196 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 213 BH-5 BD-14 118 0.139 0.121 Comparative BH-5-a BD-14 78 0.139 0.121 Example 213

Example 214 and Comparative Example 214

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 197 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 214 BH-6 BD-14 106 0.139 0.121 Comparative BH-6-a BD-14 70 0.139 0.121 Example 214

Example 215 and Comparative Example 215

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 198 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 215 BH-7 BD-14 102 0.139 0.121 Comparative BH-7-a BD-14 70 0.139 0.121 Example 215

Example 216 and Comparative Example 216

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 199 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 216 BH-8 BD-14 81 0.139 0.121 Comparative BH-8-a BD-14 54 0.139 0.121 Example 216

Example 217 and Comparative Example 217

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 200 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 217 BH-9 BD-14 72 0.139 0.121 Comparative BH-9-a BD-14 54 0.139 0.121 Example 217

Example 218 and Comparative Example 218

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 201 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 218 BH-10 BD-14 72 0.139 0.121 Comparative BH-10-a BD-14 53 0.139 0.121 Example 218

Example 219 and Comparative Example 219

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 202 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 219 BH-11 BD-14 68 0.139 0.121 Comparative BH-11-a BD-14 50 0.139 0.121 Example 219

Example 220 and Comparative Example 220

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 203 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 220 BH-12 BD-14 63 0.139 0.122 Comparative BH-12-a BD-14 43 0.139 0.122 Example 220

Example 221 and Comparative Example 221

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 204 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 221 BH-13 BD-14 49 0.139 0.121 Comparative BH-13-a BD-14 40 0.139 0.121 Example 221

Example 222 and Comparative Example 222

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 205 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 222 BH-14 BD-14 101 0.139 0.121 Comparative BH-14-a BD-14 67 0.139 0.121 Example 222

Example 223 and Comparative Example 223

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 206 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 223 BH-15 BD-14 73 0.139 0.121 Comparative BH-15-a BD-14 48 0.139 0.121 Example 223

Example 224 and Comparative Example 224

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 207 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 224 BH-16 BD-14 68 0.139 0.121 Comparative BH-16-a BD-14 48 0.139 0.121 Example 224

Example 225

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the fallowing Table.

TABLE 208 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 225 BH-17 BD-14 104 0.139 0.121

Example 226 and Comparative Example 226

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 209 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 226 BH-1 BD-15 63 0.140 0.094 Comparative BH-1-a BD-15 44 0.140 0.094 Example 226

Example 227 and Comparative Example 227

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 210 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 227 BH-2 BD-15 33 0.140 0.094 Comparative BH-2-a BD-15 25 0.140 0.094 Example 227

Example 228 and Comparative Example 228

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 211 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 228 BH-3 BD-15 29 0.140 0.094 Comparative BH-3-a BD-15 21 0.140 0.094 Example 228

Example 229 and Comparative Example 229

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 212 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 229 BH-4 BD-15 32 0.140 0.094 Comparative BH-4-a BD-15 25 0.140 0.094 Example 229

Example 230 and Comparative Example 230

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 213 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 230 BH-5 BD-15 66 0.140 0.094 Comparative BH-5-a BD-15 44 0.140 0.094 Example 230

Example 231 and Comparative Example 231

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 214 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 231 BH-6 BD-15 63 0.140 0.094 Comparative BH-6-a BD-15 41 0.140 0.094 Example 231

Example 232 and Comparative Example 232

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 215 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 232 BH-7 BD-15 63 0.140 0.094 Comparative BH-7-a BD-15 41 0.140 0.094 Example 232

Example 233 and Comparative Example 233

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 216 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 233 BH-8 BD-15 45 0.140 0.094 Comparative BH-8-a BD-15 34 0.140 0.094 Example 233

Example 234 and Comparative Example 234

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 217 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 234 BH-9 BD-15 47 0.140 0.094 Comparative BH-9-a BD-15 32 0.140 0.094 Example 234

Example 235 and Comparative Example 235

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 218 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 235 BH-10 BD-15 42 0.140 0.094 Comparative BH-10-a BD-15 30 0.140 0.094 Example 235

Example 236 and Comparative Example 236

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 219 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 236 BH-11 BD-15 37 0.140 0.094 Comparative BH-11-a BD-15 28 0.140 0.094 Example 236

Example 237 and Comparative Example 237

Except that the compounds shown in fallowing table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 220 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 237 BH-12 BD-15 35 0.140 0.095 Comparative BH-12-a BD-15 27 0.140 0.095 Example 237

Example 238 and Comparative Example 238

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 221 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 238 BH-13 BD-15 33 0.140 0.094 Comparative BH-13-a BD-15 27 0.140 0.094 Example 238

Example 239 and Comparative Example 239

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 222 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 239 BH-14 BD-15 63 0.140 0.094 Comparative BH-14-a BD-15 43 0.140 0.094 Example 239

Example 240 and Comparative Example 240

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 223 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 240 BH-15 BD-15 41 0.140 0.094 Comparative BH-15-a BD-15 30 0.140 0.094 Example 240

Example 241 and Comparative Example 241

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 224 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 241 BH-16 BD-15 38 0.140 0.094 Comparative BH-16-a BD-15 26 0.140 0.094 Example 241

Example 242

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 225 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 242 BH-17 BD-11 67 0.140 0.094

Example 243 and Comparative Example 243

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 226 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 243 BH-1 BD-16 95 0.141 0.098 Comparative BH-1-a BD-16 62 0.141 0.098 Example 243

Example 244 and Comparative Example 244

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 227 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 244 BH-2 BD-16 54 0.141 0.098 Comparative BH-2-a BD-16 35 0.141 0.098 Example 244

Example 245 and Comparative Example 245

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 228 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 245 BH-3 BD-16 45 0.141 0.098 Comparative BH-3-a BD-16 35 0.141 0.098 Example 245

Example 246 and Comparative Example 246

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 229 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 246 BH-4 BD-16 45 0.141 0.098 Comparative BH-4-a BD-16 30 0.141 0.098 Example 246

Example 247 and Comparative Example 247

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 230 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 247 BH-5 BD-16 104 0.141 0.098 Comparative BH-5-a BD-16 70 0.141 0.098 Example 247

Example 248 and Comparative Example 248

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 231 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 248 BH-6 BD-16 92 0.141 0.098 Comparative BH-6-a BD-16 60 0.141 0.098 Example 248

Example 249 and Comparative Example 249

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 232 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 249 BH-7 BD-16 95 0.141 0.098 Comparative BH-7-a BD-16 70 0.141 0.098 Example 249

Example 250 and Comparative Example 250

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 233 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 250 BH-8 BD-16 72 0.141 0.098 Comparative BH-8-a BD-16 50 0.141 0.098 Example 250

Example 251 and Comparative Example 251

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 234 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 251 BH-9 BD-16 68 0.141 0.098 Comparative BH-9-a BD-16 51 0.141 0.098 Example 251

Example 252 and Comparative Example 252

Except that the compounds shown in following (able were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 235 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 252 BH-10 BD-16 63 0.141 0.098 Comparative BH-10-a BD-16 48 0.141 0.098 Example 252

Example 253 and Comparative Example 253

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 236 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 253 BH-11 BD-16 54 0.141 0.098 Comparative BH-11-a BD-16 42 0.141 0.098 Example 253

Example 254 and Comparative Example 254

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 237 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 254 BH-12 BD-16 55 0.141 0.098 Comparative BH-12-a BD-16 37 0.141 0.098 Example 254

Example 255 and Comparative Example 255

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 238 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 255 BH-13 BD-16 50 0.141 0.098 Comparative BH-13-a BD-16 33 0.141 0.098 Example 255

Example 256 and Comparative Example 256

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 239 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 256 BH-14 BD-16 90 0.141 0.098 Comparative BH-14-a BD-16 61 0.141 0.098 Example 256

Example 257 and Comparative Example 257

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 240 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 257 BH-15 BD-16 70 0.141 0.098 Comparative BH-15-a BD-16 47 0.141 0.098 Example 257

Example 258 and Comparative Example 258

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 241 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 258 BH-16 BD-16 63 0.141 0.098 Comparative BH-16-a BD-16 42 0.141 0.098 Example 258

Example 259

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 242 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 259 BH-17 BD-16 99 0.141 0.098

Example 260 and Comparative Example 260

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 243 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 260 BH-1 BD-17 95 0.140 0.096 Comparative BH-1-a BD-17 63 0.140 0.096 Example 260

Example 261 and Comparative Example 261

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 244 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 261 BH-2 BD-17 44 0.140 0.096 Comparative BH-2-a BD-17 30 0.140 0.096 Example 261

Example 262 and Comparative Example 262

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 245 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 262 BH-3 BD-17 45 0.140 0.096 Comparative BH-3-a BD-17 30 0.140 0.096 Example 262

Example 263 and Comparative Example 263

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 246 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 263 BH-4 BD-17 45 0.140 0.096 Comparative BH-4-a BD-17 30 0.140 0.096 Example 263

Example 264 and Comparative Example 264

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 247 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 264 BH-5 BD-17 105 0.140 0.096 Comparative BH-5-a BD-17 71 0.140 0.096 Example 264

Example 265 and Comparative Example 265

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 248 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 265 BH-6 BD-17 90 0.140 0.096 Comparative BH-6-a BD-17 60 0.140 0.096 Example 265

Example 266 and Comparative Example 266

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 249 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 266 BH-7 BD-17 90 0.140 0.096 Comparative BH-7-a BD-17 63 0.140 0.096 Example 266

Example 267 and Comparative Example 267

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 250 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 267 BH-8 BD-17 72 0.140 0.096 Comparative BH-8-a BD-17 50 0.140 0.096 Example 267

Example 268 and Comparative Example 268

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 251 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 268 BH-9 BD-17 72 0.140 0.096 Comparative BH-9-a BD-17 50 0.140 0.096 Example 268

Example 269 and Comparative Example 269

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 252 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 269 BH-10 BD-17 59 0.140 0.096 Comparative BH-10-a BD-17 48 0.140 0.096 Example 269

Example 270 and Comparative Example 270

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dcpant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 253 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 270 BH-11 BD-17 59 0.140 0.096 Comparative BH-11-a BD-17 40 0.140 0.096 Example 270

Example 271 and Comparative Example 271

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 254 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 271 BH-12 BD-17 56 0.140 0.096 Comparative BH-12-a BD-17 38 0.140 0.096 Example 271

Example 272 and Comparative Example 272

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 255 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 272 BH-13 BD-17 50 0.140 0.096 Comparative BH-13-a BD-17 34 0.140 0.096 Example 272

Example 273 and Comparative Example 273

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 256 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 273 BH-14 BD-17 97 0.140 0.096 Comparative BH-14-a BD-17 63 0.140 0.096 Example 273

Example 274 and Comparative Example 274

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 257 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 274 BH-15 BD-17 61 0.140 0.096 Comparative BH-15-a BD-17 42 0.140 0.096 Example 274

Example 275 and Comparative Example 275

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 258 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 275 BH-16 BD-17 67 0.140 0.096 Comparative BH-16-a BD-17 45 0.140 0.096 Example 275

Example 276

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 259 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 276 BH-17 BD-17 95 0.140 0.096

Example 277 and Comparative Example 277

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 260 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 277 BH-1 BD-18 77 0.143 0.109 Comparative BH-1-a BD-18 52 0.143 0.109 Example 277

Example 278 and Comparative Example 278

Except that the compounds shown in fallowing table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the fallowing Table.

TABLE 261 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 278 BH-2 BD-18 36 0.143 0.109 Comparative BH-2-a BD-18 29 0.143 0.109 Example 278

Example 279 and Comparative Example 279

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The resists are shown in the following Table.

TABLE 262 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 279 BH-3 BD-18 36 0.143 0.109 Comparative BH-3-a BD-18 25 0.143 0.109 Example 279

Example 280 and Comparative Example 280

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 263 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 280 BH-4 BD-18 33 0.143 0.109 Comparative BH-4-a BD-18 24 0.143 0.109 Example 280

Example 281 and Comparative Example 281

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 264 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 281 BH-5 BD-18 81 0.143 0.109 Comparative BH-5-a BD-18 53 0.143 0.109 Example 281

Example 282 and Comparative Example 282

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 265 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 282 BH-6 BD-18 72 0.143 0.109 Comparative BH-6-a BD-18 50 0.143 0.109 Example 282

Example 283 and Comparative Example 283

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 266 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 283 BH-7 BD-18 72 0.143 0.109 Comparative BH-7-a BD-18 52 0.143 0.109 Example 283

Example 284 and Comparative Example 284

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 267 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 284 BH-8 BD-18 54 0.143 0.109 Comparative BH-8-a BD-18 40 0.143 0.109 Example 284

Example 285 and Comparative Example 285

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 268 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 285 BH-9 BD-18 54 0.143 0.109 Comparative BH-9-a BD-18 37 0.143 0.109 Example 285

Example 286 and Comparative Example 286

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 269 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 286 BH-10 BD-18 51 0.143 0.109 Comparative BH-10-a BD-18 35 0.143 0.109 Example 286

Example 287 and Comparative Example 287

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 270 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 287 BH-11 BD-18 48 0.143 0.109 Comparative BH-11-a BD-18 31 0.143 0.109 Example 287

Example 288 and Comparative Example 288

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 271 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 288 BH-12 BD-18 43 0.143 0.110 Comparative BH-12-a BD-18 31 0.143 0.110 Example 288

Example 289 and Comparative Example 289

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 272 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 289 BH-13 BD-18 36 0.143 0.109 Comparative BH-13-a BD-18 25 0.143 0.109 Example 289

Example 290 and Comparative Example 290

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 273 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 290 BH-14 BD-18 71 0.143 0.109 Comparative BH-14-a BD-18 48 0.143 0.109 Example 290

Example 291 and Comparative Example 291

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 274 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 291 BH-15 BD-18 56 0.143 0.109 Comparative BH-15-a BD-18 38 0.143 0.109 Example 291

Example 292 and Comparative Example 292

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL devices were fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 275 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 292 BH-16 BD-18 46 0.143 0.109 Comparative BH-16-a BD-18 32 0.143 0.109 Example 292

Example 293 and Comparative Example 293

Except that the compounds shown in following table were used as the materials of the emitting layer (host material and dopant material), the organic EL device was fabricated and evaluated in the same manner as in Example 1. The results are shown in the following Table.

TABLE 276 Emitting layer Host Dopant Chromaticity material material LT95(h) CIEx CIEy Example 293 BH-17 BD-18 75 0.143 0.109

From the results of Tables 1 to 276, it can be recognized that, if the compound represented by the formula (1) (host material) having a deuterium atom at the particular position is used in combination with the particular dopant material in the emitting layer of the organic EL device, the lifetime of the organic EL device is prolonged compared with the case where the compound (host material) having no deuterium atom at the particular position is used in combination with the corresponding dopant material.

Several embodiments and/or examples of the present invention have been described in detail above. However, without substantially departing from novel teachings and effects of the present invention, the person skilled in the art can readily make a number of modifications to the embodiments and/or examples which are exemplifications of these teachings and effects. Thus, these modifications are inducted in the scope of the present invention.

The documents described in this specification and the contents of the application that serves as the basis of priority claim under Paris convention are incorporated herein by reference in its entirety. 

1. An organic electroluminescence device comprising: a cathode, an anode, and an emitting layer disposed between the cathode and the anode, wherein the emitting layer comprises a compound represented by the following formula (1) and one or more compounds selected from the group consisting of compounds represented by each of formulas (11), (21), (31), (41), (51), (61), (71) and (81):

wherein in the formula (1), R₁ to R₈ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; when two or more of R₉₀₁ to R₉₀₇ exist, two or more of R₉₀₁ to R₉₀₇ may be the same with or different from each other; at least one of R₁ to R₈ is a deuterium atom; two or more adjacent groups of R₁ to R₄ and two or more adjacent groups of R₅ to R₈ do not form a ring; L₁ and L₂ are independently a single bond, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms; Ar is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; one of R₁₁ to R₁₈ is a single bond bonding to L₂; R₁₁ to R₁₈ which are not single bonds bonding to L₂ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in R₁ to R₈; and two or more adjacent groups of R₁₁ to R₁₈ do not form a ring;

wherein, in the formula (11), one or more pairs of two or more adjacent groups of R₁₀₁ to R₁₁₀ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring; at least one of R₁₀₁ to R₁₁₀ is a monovalent group represented by the formula (12); R₁₀₁ to R₁₁₀ that do not form the substituted or unsubstituted, saturated or unsaturated ring and that are not a monovalent group represented by the following formula (12) are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (12), Ar₁₀₁ and Ar₁₀₂ are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; L₁₀₁ to L₁₀₃ are independently a single bonded, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms;

wherein, in the formula (21), Z's are independently CR_(a) or N; A1 ring and A2 ring are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms; when a plurality of R_(a)s exist, one or more pairs of two or more adjacent groups of R_(a) are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring; when a plurality of R_(b)s exist, one or more pairs of two or more adjacent groups of R_(b) are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring; when a plurality of R_(c)s exist, one or more pairs of two or more adjacent groups of R_(c) are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring; n21 and n22 are independently an integer of 0 to 4; R_(a) to R_(c) that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (31), one or more pairs of two or more adjacent groups of R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted saturated or unsaturated ring; R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₃₂₁ and R₃₂₂ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (41), a ring, b ring and c ring are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms; R₄₀₁ and R₄₀₂ are independently bonded to the a ring, the b ring or the c ring to form a substituted or unsubstituted heterocyclic ring or do not form a substituted or unsubstituted heterocyclic ring; R₄₀₁ and R₄₀₂ that do not form the substituted or unsubstituted heterocyclic ring are independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;

wherein, in the formula (51), r ring is a ring represented by the formula (52) or formula (53) which is fused to an adjacent ring at an arbitrary position; q ring and s ring are independently a ring represented by the formula (54) which is fused to an adjacent ring at an arbitrary position; p ring and t ring are independently a ring represented by the formula (55) or the formula (56) which is fused to an adjacent ring at an arbitrary position; when a plurality of R₅₀₁s exist, adjacent R₅₀₁s are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring; X₅₀₁ is an oxygen atom, a sulfur atom, or NR₅₀₂; R₅₀₁ and R₅₀₂ that do not form the substituted or unsubstituted saturated or unsaturated ring are a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1); Ar₅₀₁ and Ar₅₀₂ are independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; L₅₀₁ is a substituted or unsubstituted alkylene group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenylene group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynylene group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkylene group having 3 to 50 ring carbon atoms, a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 50 ring atoms; m1 is an integer of 0 to 2, m2 is an integer of 0 to 4, m3s are independently an integer of 0 to 3, and m4s are independently an integer of 0 to 5; when a plurality of R₅₀₁s exist, R₅₀₁s may be the same or different;

wherein, in the formula (61), at least one pair of R₆₀₁ and R₆₀₂, R₆₀₂ and R₆₀₃, and R₆₀₃ and R₆₀₄ are bonded with each other to form a divalent group represented by the formula (62); at least one pair of R₆₀₅ and R₆₀₆, R₆₀₆ and R₆₀₇, and R₆₀₇ and R₆₀₈ are bonded with each other to form a divalent group represented by formula (63);

at least one of R₆₀₁ to R₆₀₄ that does not form the divalent group represented by the formula (62), and R₆₁₁ to R₆₁₄ is a monovalent group represented by the following formula (64); at least one of R₆₀₅ to R₆₀₈ that do not form the divalent group represented by the formula (63), and R₆₂₁ to R₆₂₄ is a monovalent group represented by the following formula (64); X₆₀₁ is an oxygen atom, a sulfur atom, or NR₆₀₉; R₆₀₁ to R₆₀₈ that do not form the divalent group represented by the formulas (62) and (63) and that is not the monovalent group represented by the formula (64), Ren to R₆₁₄ and R₆₂₁ to R₆₂₄ that are not the monovalent group represented by the formula (64), and R₆₀₉ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (64), Ar₆₀₁ and Ar₆₀2 are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; L₆₀₁ to L₆₀₃ are independently a single bonded, a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms, or a divalent linking group formed by bonding 2 to 4 above mentioned groups;

wherein, in the formula (71), A₇₀₁ ring and A702 ring are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms; One or more rings selected from the group consisting of A₇₀₁ ring and A702 ring are bonded to the bond * of the structure represented by the following formula (72);

wherein, in the formula (72), A₇₀₃ rings are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms; X₇₀₁ is NR₇₀₃, C(R₇₀₄)(R₇₀₅), Si(R₇₀₆) (R₇₀₇), Ge(R₇₀₈) (R₇₀₉), O, S or Se; R₇₀₁ and R₇₀₂ are bonded with each other to form a substituted or unsubstituted, saturated or unsaturated ring or do not form a substituted or unsubstituted saturated or unsaturated ring; R₇₀₁ and R₇₀₂ that do not form the substituted or unsubstituted, saturated or unsaturated ring, and R₇₀₃ to R₇₀₉ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (81), A₈₀₁ ring is a ring represented by the formula (82) which is fused to an adjacent ring at an arbitrary position; A₈₀₂ ring is a ring represented by the formula (83) which is fused to an adjacent ring at an arbitrary position; two bonds * bond to A₈₀₃ ring at an arbitrary position; X₈₀₁ and X₈₀₂ are independently C(R₈₀₃)(R₈₀₄), Si(R₈₀₅)(R₈₀₆), an oxygen atom, or a sulfur atom; A₈₀₃ ring is a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic ring having 5 to 50 ring atoms; Ar₈₀₁ is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₈₀₁ to R₈₀₆ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1); m801 and m802 are independently an integer of 0 to 2; when these are 2, a plurality of R₈₀₁s or R₈₀₂s may be the same or different; a801 is an integer of 0 to 2; when a801 is 0 or 1, the structure in the parentheses indicated by “3-a801” may be the same as or different from each other; when a801 is 2, Ar₈₀₁s may be the same or different from each other.
 2. The organic electroluminescence device according to claim 1, wherein in the formula (1), at least two of R₁ to R₈ are deuterium atoms.
 3. The organic electroluminescence device according to claim 1, wherein in the formula (1), R₁ to R₈ are all deuterium atoms.
 4. The organic electroluminescence device according to claim 1, wherein in the formula (1), one or more of L₁ and L₂ are a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms in which at least one of hydrogen atoms is a deuterium atom, or a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms in which at least one of hydrogen atoms is a deuterium atom.
 5. The organic electroluminescence device according to claim 1, wherein in the formula (1), wherein L₁ and L₂ are independently a single bond, or a substituted or unsubstituted arylene group having 6 to 14 ring carbon atoms.
 6. The organic electroluminescence device according to claim 1, wherein Ar is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms in which at least one of hydrogen atoms is a deuterium atom, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms in which at least one of hydrogen atoms is a deuterium atom.
 7. The organic electroluminescence device according to claim 1, wherein in the formula (1), Ar is a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.
 8. The organic electroluminescence device according to claim 7, wherein in the formula (1), Ar is selected from groups represented by any of the following formulas (a1) to (a4):

wherein in the formulas (a1) to (a4), “*” is a single bond which bonds to L₁; R₂₁ is a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1); m1 is an integer of 0 to 4; m2 is an integer of 0 to 5; m3 is an integer of 0 to 7; when each of m1 to m3 is two or more, a plurality of R₂₁'s are the same as or different from each other; and when each of m1 to m3 is 2 or more, adjacent R₂₁'s form a substituted or unsubstituted, saturated or unsaturated ring by bonding with each other, or do not form a substituted or unsubstituted, saturated or unsaturated ring.
 9. The organic electroluminescence device according to claim 1, wherein in the formula (1), R₁₁ to R₁₈ which are not a single bond bonded with L₂ are hydrogen atoms.
 10. The organic electroluminescence device according to claim 1, wherein in the formula (1), R₁₁ to R₁₈ which are not a single bond bonded with L₂ are deuterium atoms.
 11. The organic electroluminescence device according to claim 1, wherein the compound represented by the formula (1) is a compound represented by the following formula (2):

wherein in the formula (2), R₁ to R₈, Ar, L₁ and L₂ are as defined in the formula (1).
 12. The organic electroluminescence device according to claim 1, wherein the compound represented by the formula (1) is a compound represented by the following formula (3):

wherein in the formula (3), Ar, L₁ and L₂ are as defined in the formula (1).
 13. The organic electroluminescence device according to claim 1, wherein relative to the total amount of the compound represented by formula (1) and a compound having a structure same as the compound represented by the formula (1) and containing only protium atoms as hydrogen atoms, in the emitting layer, the content ratio of the latter is 99 mol % or less.
 14. The organic electroluminescence device according to claim 1, wherein in the formula (11), two of R₁₀₁ to R₁₁₀ are a group represented by the formula (12).
 15. The organic electroluminescence device according to claim 1, wherein the compound represented by the formula (11) is a compound represented by the following formula (13):

wherein in the formula (13), R₁₁₁ to R₁₁₈ in the formula (11) are the same as R₁₀₁ to R₁₁₀ that are not a monovalent group represented by the formula (12); and Ar₁₀₁, Ar₁₀₂, L₁₀₁, L₁₀₂ and L₁₀₃ are as defined in the formula (12).
 16. The organic electroluminescence device according to claim 15, wherein the compound represented by the formula (13) is a compound represented by the following formula (14):

wherein in the formula (14), R₁₁₁ to R₁₁₈ are as defined in the formula (13); and Ar₁₀₁, Ar₁₀₂, L₁₀₂ and L₁₀₃ are as defined in the formula (12).
 17. The organic electroluminescence device according to claim 15, wherein the compound represented by the formula (13) is a compound represented by the formula (15):

wherein in the formula (15), R₁₁₁ to R₁₁₈ are as defined in the formula (13); and Ar₁₀₁ and Ar₁₀₂ are as defined in the formula (12).
 18. The organic electroluminescence device according to claim 15, wherein the compound represented by the formula (13) is a compound represented by the formula (17):

wherein in the formula (17), R₁₁₁ to R₁₁₈ are as defined in the formula (13); one ore more pairs of adjacent two or more of R₁₂₁ to R₁₂₇ form a substituted or unsubstituted, saturated or unsaturated ring by bonding with each other, or do not form a substituted or unsubstituted, saturated or unsaturated ring; R₁₂₁ to R₁₂₇ that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1); and R₁₃₁ to R₁₃₅ are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; R₉₀₁ to R₉₀₇ are as defined in the formula (1).
 19. The organic electroluminescence device according to claim 1, wherein in the formula (41), the a ring, the b ring and the c ring are independently a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50 ring carbon atoms.
 20. The organic electroluminescence device according to claim 1, wherein in the formula (41), R₄₀₁ and R₄₀₂ are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.
 21. The organic electroluminescence device according to claim 1, wherein in the formula (41), R₄₀₁ and R₄₀₂ are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.
 22. The organic electroluminescence device according to claim 1, wherein the compound represented by the formula (41) is a compound represented by the following formula (42):

wherein in the formula (42), R_(401A) forms a substituted or unsubstituted heterocyclic ring by bonding with one or more selected from the group consisting of R₄₁₁ and R₄₂₁, or does not form a substituted or unsubstituted heterocyclic ring; R_(402A) forms a substituted or unsubstituted heterocyclic ring by bonding with one or more selected from the group consisting of R₄₁₃ and R₄₁₄, or does not form a substituted or unsubstituted heterocyclic ring; R_(401A) and R_(402A) that do not form the substituted or unsubstituted heterocyclic ring are independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; one or more pairs of adjacent two or more of R₄₁₁ to R-m form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring; R₄₁₁ to R₄₂₁ that do not form the substituted or unsubstituted heterocyclic ring and the substituted or unsubstituted, saturated or unsaturated ring are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and R₉₀₁ to R₉₀₇ are as defined in the formula (1).
 23. The organic electroluminescence device according to claim 1, wherein the compound represented by the formula (41) is a compound represented by the following formula (43):

wherein in the formula (43) R₄₃₁ forms a substituted or unsubstituted heterocyclic ring by bonding with R₄₄₆, or does not form a substituted or unsubstituted heterocyclic ring; R₄₃₃ forms a substituted or unsubstituted heterocyclic ring by bonding with R₄₄₇, or does not form a substituted or unsubstituted heterocyclic ring; R₄₃₄ forms a substituted or unsubstituted heterocyclic ring by bonding with R₄₅₁, or does not form a substituted or unsubstituted heterocyclic ring; R₄₄₁ forms a substituted or unsubstituted heterocyclic ring by bonding with R₄₄₂, or does not form a substituted or unsubstituted heterocyclic ring; one or more pairs of adjacent two or more of R₄₃₁ to R₄₅₁ form a substituted or unsubstituted, saturated or unsaturated ring by bonding with each other, or do not form a substituted or unsubstituted, saturated or unsaturated ring; R₄₃₁ to R₄₅₁ that do not form the substituted or unsubstituted heterocyclic ring or the substituted or unsubstituted, saturated or unsaturated ring are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, —Si(R₉₀₁)(R₉₀₂)(R₉₀₃), —O—(R₉₀₄), —S—(R₉₀₅), —N(R₉₀₆)(R₉₀₇), a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms; and R₉₀₁ to R₉₀₇ are as defined in the formula (1).
 24. The organic electroluminescence device according to claim 1, which further comprises a hole-transporting layer between the anode and the emitting layer.
 25. The organic electroluminescence device according to claim 1, which further comprises an electron-transporting layer between the cathode and the emitting layer.
 26. An electronic apparatus wherein the organic electroluminescence device according to claim 1 is provided. 